No data available.
Please log in to see this content.
You have no subscription access to this content.
No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
Ratio of Forward and Reverse Rate Coefficients and the Equilibrium Constant
1.A. A. Westenberg and N. de Haas, J. Chem. Phys. 48, 4405 (1968).
2.The ratios of forward and reverse rate coefficients for molecular dissociation reactions have been shown to be equal to the equilibrium constant after rather long temperature extrapolations were made. See K. L. Wray, J. Chem. Phys. 38, 1518 (1963);
2.J. H. Kiefer and R. W. Lutz, J. Chem. Phys. 42, 1709 (1965); , J. Chem. Phys.
2.G. L. Schott and P. F. Bird, J. Chem. Phys. 41, 2869 (1964). But the precision of shock‐tube measurements is generally lower than low‐temperature kinetics measurements and in some cases is not much better than the uncertainty is almost as large as the factor of 2–3 which is significant in the work of Westenberg and de Haas.
3.A. A. Noyes and M. S. Sherrill, A Course of Study in Chemical Principles (The MacMillan Co., New York, 1938), p. 408;
3.H. J. Schumacher, Chemische Gasreaktionen (Edwards Brothers, Inc., Ann Arbor, Mich., 1943), p. 279;
3.P. G. Ashmore, Principles of Reaction Kinetics (The Royal Institute of Chemistry, London, 1967), 2nd ed., p. 23; see other texts.
4.See L. S. Kassel, Kinetics of Homogeneous Gas Reactions (Reinhold Publ. Corp., New York, 1932), pp. 148–155.
5.A. H. Taylor and R. H. Crist, J. Am. Chem. Soc. 65, 1377 (1941).
6.For the purpose here it is immaterial whether the reaction is considered as or since where The rate coefficients were incorrect because of the chain sequence.
7.S. W. Benson and R. Srinivasan, J. Chem. Phys. 23, 200 (1955).
8.(a) J. H. Sullivan, J. Chem. Phys. 30, 1292 (1959);
8.(b) J. H. Sullivan, 36, 1925 (1962)., J. Chem. Phys.
9.Reference 8(a), p. 1298.
10.G. B. Kistiakowsky, J. Am. Chem. Soc. 50, 2315 (1928).
11.J. H. Sullivan, J. Chem. Phys. 46, 73 (1967).
12.Selected Values of Chemical Thermodynamic Properties (National Bureau of Standards, Washington, D.C.), Ser. III, 31 March 1949; and I, 1 March 1954; HI, 30 June 1948.
Article metrics loading...
Full text loading...
Most read this month
Most cited this month