No data available.
Please log in to see this content.
You have no subscription access to this content.
No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
ESR spectrum and structure of the n ‐propyl radical
1.For a general review, see P. B. Ayscough, Electron Spin Resonance in Chemistry (Methuen, London, 1967), Chap. 9.
2.E. L. Cochran, F. J. Adrian, and V. A. Bowers, J. Chem. Phys. 34, 1161 (1961).
3.C. A. McDowell, P. Raghunathan, and K. Shimokoshi, J. Chem. Phys. 58, 114 (1972).
4.P. H. Kasai and E. B. Whipple, J. Am. Chem. Soc. 89, 1033 (1967).
5.(a) S. N. Foner, E. L. Cochran, V. A. Bowers, and C. K. Jen, J. Chem. Phys. 32, 963 (1960);
5.S. N. Foner, E. L. Cochran, V. A. Bowers, and C. K. Jen, Phys. Rev. 112, 1169 (1958).
6.J. E. Wertz and J. R. Bolton, Electron Spin Resonance: Elementary Theory and Applications (McGraw‐Hill, New York, 1972), Chap. 7.
7.Calculated using the method of Lefebvre [R. Lefebvre, J. Chem. Phys. 33, 1826 (1960)], modified to include an anisotropic g factor and a number of anisotropic hfs interactions.
8.F. J. Adrian, E. L. Cochran, and V. A. Bowers, J. Chem. Phys. 43, 462 (1965). The procedure described here for the case of a single spin with is readily extended to a number of spins.
9.Reference 6, Chap. 6.
10.This value is in good agreement with the value given by R. W. Fessenden and R. H. Schuler, J. Chem. Phys. 39, 2147 (1963).
11.H. M. McConnell, C. Heller, T. Cole, and R. W. Fessenden, J. Am. Chem. Soc. 82, 766 (1960);
11.A. Horsfield, J. R. Morton, and D. H. Whiffen, Mol. Phys. 4, 327 (1961).
12.In this calculation, it is assumed that the α carbon atom is hybridized so that the unpaired electron occupies a pure pπ orbital, and the bond angle is 120°.
13.Reference 1, pp. 76–77.
14.In this calculation, it is assumed that the β carbon is hybridized so that the bond angle is 109.5°.
15.H. M. McConnell and J. Strathdee, Mol. Phys. 2, 129 (1959),
15.with corrections given by R. M. Pitzer, C. W. Kern, and W. N. Lipscomb, J. Chem. Phys. 37, 267 (1962).
16.R. W. Fessenden, J. Chem. Phys. 71, 74 (1967).
17.M. Barfield, J. Chem. Phys. 53, 3836 (1970),
17.M. Barfield, with correction in J. Chem. Phys. 55, 4682 (1971).
18.H. M. McConnell and R. E. Robertson, J. Phys. Chem. 61, 1018 (1957).
Article metrics loading...
Full text loading...
Most read this month
Most cited this month