Hydrodynamic thickness of adsorbed polymers
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5.(b)All theoretical and experimental bases for the exponential distribution have been given in the case of monolayer adsorption; multilayer surface adsorption may also possibly occur in practice [Cf. A. Silberberg, J. Coll. Interface Sci. 38, 217 (1972)]; as, however, no exact treatment has been derived for the latter case, the model used here cannot a priori be extended to the case of extensive multilayer adsorption.
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14.If and are determined by measureing the volume flow of the pure solvent and solution, respectively, the ratio should then be multiplied by the viscosity of the solution divided by that of the solvent.
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16.Equation (10) is obtained by writing and by taking for n the value b/l which renders maxima. The factor 2.3 is found by numerical computation of series (9).
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21.Equation (25) was derived for one essentially infinitely long polymer chain and large loop sizes. Its application to finite chain length is only justified for a range of values where b does not reach prohibitively large values compared to the total chain length, and loop sizes are still large enough to justify the use of the Gaussian approximation for random walks.
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23.R. R. Stromberg, in Treatise on Adhesion and Adhesives, edited by R. L. Patrick (Marcel Dekker, New York, 1967), Chap. 3.
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