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The Explosion of Ethyl Azide in the Presence of Diethyl Ether
1.(a) H. C. Campbell and O. K. Rice, J. Am. Chem. Soc. 57, 1044 (1935);
1.(b) Rice, Allen, and Campbell, J. Am. Chem. Soc. 57, 2212 (1935)., J. Am. Chem. Soc.
2.A. O. Allen and O. K. Rice, J. Am. Chem. Soc. 57, 310 (1935).
3.J. A. Leermakers, J. Am. Chem. Soc. 55, 2719 (1933).
4.N. N. Semenoff, Zeits. f. Physik 48, 571 (1928).
5.O. M. Todes, Acta Physicochim. U.R.S.S. 5, 785 (1936).
5.A. Appin, J. Chariton, and O. M. Todes, Acta Physicochim. U.R.S.S. 5, 655 (1936)., Acta Physicochim. URSS
6.We use cal. per mole and log This conforms with our previous work.1a The log is obtained from Leermaker’s curves,3 as explained above. being the reaction rate at temperature where is small compared to is calculated from the approximate but very nearly correct equation
7.See Landolt‐Börnstein, Tabellen.
8.F. R. Bichowsky and F. D. Rossini, Thermochemistry of Chemical Substances (Reinhold Publishing Co. 1936).
9.It is, of course, the quiet decomposition which goes during the induction period and determines Q.
10.From bond energies (tabulation of Rice, Electronic Structure and Chemical Binding (McGraw‐Hill Book Co., in press)), and the difference in the heats of formation of and
11.Frank‐Kameneckij, Comptes Rendus (Doklady) Acad. Sci. U.R.S.S. 18, 413 (1938).
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