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Size distribution for aggregates of associating polymers. II. Linear packing
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10.A related problem involves the micellization of diblock copolymers in solvents of simple or homopolymer molecules. See (a) L. Leibler, H. Orland, and J. C. Wheeler, J. Chem. Phys. 79, 3550 (1983);
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17.Strictly speaking, the factor in the blob form of the free energy should be replaced by the partition function exponent For however, we expect to be the correct limiting form. In two‐dimension, a similar blob argument leads to a factor in front of In N. This can be compared to the conjectured exact value for star polymers in two‐dimension: See, A. Miyake and K. F. Freed, Macromolecules 16, 1228 (1983);
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18.A Flory‐type argument by balancing the elastic energy and the excluded volume interaction leads to a similar form for the free energy of an infinite cylinder: If we assume that the finite aggregate takes the shape of a spherocylinder with a uniform radius, then the end cap free energy is: This is to be compared with Eq. (33).
19.A. L. R. Bug(unpublishedotes).
20.S. T. Milner (private communication).
21.See, for example, B. Jönsson P.‐G. Nilsson, B. Lindman, L. Guldbrand, and H. Wennerstrom, p. 3 of Ref. 7.
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