No data available.
Please log in to see this content.
You have no subscription access to this content.
No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
Theory of rotational coherence spectroscopy as implemented by picosecond fluorescence depletion schemes
1.(a) P. M. Felker, J. S. Baskin, and A. H. Zewail, J. Phys. Chem. 90, 724 (1986);
1.(b) J. S. Baskin, P. M. Felker, and A. H. Zewail, J. Chem. Phys. 84, 4708 (1986).
2.(a) P. M. Felker and A. H. Zewail, J. Chem. Phys. 86, 2460 (1987);
2.(b) J. S. Baskin, P. M. Felker, and A. H. Zewail, J. Chem. Phys. 86, 2483 (1987)., J. Chem. Phys.
3.J. S. Baskin and A. H. Zewail, J. Phys. Chem. 93, 5701 (1989).
4.N. F. Scherer, L. Khundkar, T. Rose, and A. H. Zewail, J. Phys. Chem. 91, 6478 (1987).
5.(a) M. J. Cote, J. F. Kauffman, P. G. Smith, and J. D. McDonald, J. Chem. Phys. 90, 2865 (1989);
5.(b) J. F. Kauffman, M. J. C⊚té, P. G. Smith, and J. D. McDonald, J. Chem. Phys. 90, 2874 (1989)., J. Chem. Phys.
6.L. L. Connell, T. C. Corcoran, P. W. Joireman, and P. M. Felker, Chem. Phys. Lett. 166, 510 (1990).
7.L. L. Connell, T. C. Corcoran, P. W. Joireman, and P. M. Felker, J. Phys. Chem. 94, 1229 (1990).
8.P. M. Felker, L. L. Connell, T. C. Corcoran, and P. W. Joireman, Proc. Soc. Photo.-Opt. Instrum. Eng. 1209, 53 (1990).
9.P. G. Smith and J. D. McDonald, J. Chem. Phys. 92, 3991 (1990).
10.T. C. Corcoran, L. L. Connell, G. V. Hartland, P. W. Joireman, R. A. Hertz, and P. M. Felker, Chem. Phys. Lett. 170, 139 (1990).
11.L. L. Connell, S. M. Ohline, P. W. Joireman, T. C. Corcoran, and P. M. Felker, J. Chem. Phys. 94, 4668 (1991).
12.(a) J. P. Heritage, T. K. Gustafson, and C. H. Lin, Phys. Rev. Lett. 34, 1299 (1975);
12.(b) T. K. Yee and T. K. Gustafson, Phys. Rev. A 18, 1597 (1978).
13.The theory of TRFD presented in Ref. 5(a) primarily pertains to the use of the method to monitor excited-state dynamics.
14.(a) C. Kittrell, E. Abramson, J. L. Kinsey, S. A. McDonald, D. E. Reisner, R. W. Field, and D. H. Katayama, J. Chem. Phys. 75, 2056 (1981);
14.(b) C. E. Hamilton, J. L. Kinsey, and R. W. Field, Annu. Rev. Phys. Chem. 37, 493 (1986);
14.(c) D. E. Cooper, C. M. Klimcak, and J. E. Wessel, Phys. Rev. Lett. 46, 324 (1981).
15.(a) J. Bordé and C. J. Bordé, J. Mol. Spectrosc. 78, 353 (1979);
15.(b) S. A. J. Druet and J.-P. E. Taran, Prog. Quantum Electron. 7, 1 (1981).
16.Y.-R. Shen, The Principles of Nonlinear Optics (Wiley-Interscience, New York, 1984).
17.The radiation fields are assumed to be effectively homogeneous at the sample. Also, the Doppler effect on rotational quantum beats is not significant. Hence, the spatial dependence of the is unimportant and, therefore, is suppressed.
18.By “short-excitation pulse limit” we mean that is large enough that the bandwidth of completely spans the rotational contour of the vibronic transition.
19.The assumption of time-separated pump and probe pulses allows the upper limit of the t2 integrals in Eqs. (2.5) to be extended to Similarly, evaluation of Eqs. (2.5) for times after the probe pulse has passed allows the upper limit of the t4 integrals in the equations to be extended to
20.For example, T. Hattori, A. Terasaki, and T. Kobayashi, Phys. Rev. A 35, 715 (1987).
21.A. R. Edmonds, Angular Momentum in Quantum Mechanics (Princeton University, Princeton, 1968).
22.G. W. King, R. M. Hainer, and P. C. Cross, J. Chem. Phys. 11, 27 (1943), and references therein.
23.See Eq. (B2) of Ref. 3.
24.L. A. Philips and D. H. Levy, J. Chem. Phys. 89, 85 (1988).
25.The transients are “simple” if the sample is at low temperature and the excitation pulse bandwidth spans only a single rotational band contour. When these conditions do not obtain somewhat more complicated structure can arise. See M. Gruebele, G. Roberts, M. Dantus, R. W. Bowman, and A. H. Zewail, Chem. Phys. Lett. 166, 459 (1990).
26.J. I. Steinfeld, R. N. Zare, L. Jones, M. Lesk, and W. Klemperer, J. Chem. Phys. 42, 25 (1965).
27.Again, this is assuming spectral filtering of the fluorescence in TRSRFD so that only emission from the manifold and not the manifold is detected.
Article metrics loading...
Full text loading...
Most read this month
Most cited this month