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A guided‐ion beam study of the reactions of N+ 4 with H2, HD, and D2: An evaluation of pseudo‐Arrhenius analyses of ion–molecule reaction systems
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18.Because of the effect of the nuclear spin statistics, the rotational energy distributions for and are not described by a simple Maxwell-Boltzmann (M-B) distribution. Cross sections calculated by using the rotational energy distributions with and without consideration of nuclear spin were indistinguishable. For simplicity, most of the modeling was done by ignoring nuclear spin effects for both the and rotational energy distributions.
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22.Because our detector quadrupole mass spectrometer can only be biased up to 100 V (lab) [ for ] relative to ground, it is possible that collection efficiency can drop off when the interaction energy approaches this voltage, especially if the product ions are not strongly forward scattered in the laboratory frame.
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29.Our stated one standard deviation uncertainties include averaging of different data sets, different values of n, different frequency sets, and the absolute uncertainty in the energy scale.
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