Index of content:
Volume 17, Issue 3, July 1988
Evaluated Chemical Kinetic Data for the Reactions of Atomic Oxygen O(3P) with Saturated Organic Compounds in the Gas Phase17(1988); http://dx.doi.org/10.1063/1.555810View Description Hide Description
Rate constants and mechanisms for the gas phase reactions of atomic oxygen O(3P) with organic compounds having only saturated C–C bonds are compiled and critically evaluated. Data are given for the alkanes, cycloalkanes, haloalkanes, oxygen and nitrogen containing organic compounds, and free radicals. In addition, data are given for some miscellaneous compounds containing boron,silicon, germane, and mercury. From a critical examination of the data, recommended values for rate constants are given over specified temperature intervals or at specified temperatures. Error limits are assigned to all recommended values.
17(1988); http://dx.doi.org/10.1063/1.555808View Description Hide Description
Rate constants have been compiled for reactions of various inorganic radicals produced by radiolysis or photolysis, as well as by other chemical means in aqueous solutions. Data are included for the reactions of ⋅CO2 −, , O3, ⋅N3, ⋅NH2, ⋅NO2, , , , , , , , , , , , , , , and miscellaneous related radicals, with inorganic and organic compounds.
17(1988); http://dx.doi.org/10.1063/1.555809View Description Hide Description
Experimental and theoretical cross‐section data for electron impact ionization of atoms and ions from fluorine to nickel has been assessed and earlier recommendations for light atoms and ions have been revised. Based on this assessment and, in the absence of any data, on the classical scaling laws a recommended cross section has been produced for each species. This has been used to evaluate recommended Maxwellian rate coefficients over a wide range of temperatures. Convenient analytic expressions have been obtained for the recommended cross sections and rate coefficients. The data are presented in both graphical and tabular form and estimates of the reliability of the recommended data are given.