Volume 39, Issue 2, June 2010
Index of content:
- REGULAR ARTICLES
The IUPAC-NIST Solubility Data Series: A Guide to Preparation and Use of Compilations and Evaluationsa)39(2010); http://dx.doi.org/10.1063/1.3380845View Description Hide Description
The IUPAC-NIST Solubility Data Series (SDS) is an ongoing project that provides comprehensive reviews of published data for solubilities of gases, liquids and solids in liquids or solids. Data are compiled in a uniform format, evaluated and, where data from independent sources agree sufficiently, recommended values are proposed. This paper is a guide to the SDS and is intended for the benefit of both those who use the SDS as a source of critically evaluated solubility data and who prepare compilations and evaluations for future volumes. A major portion of this paper presents terminology and nomenclature currently recommended by IUPAC and other international bodies and relates these to obsolete forms that appear in the older solubility literature. In addition, this paper presents a detailed guide to the criteria and procedures used in data compilation, evaluation, and presentation and considers special features of solubility in , , and systems. In the past, much of this information was included in introductory sections of individual volumes of the SDS. However, to eliminate repetitive publication, this information has been collected, updated, and expanded for separate publication here.
39(2010); http://dx.doi.org/10.1063/1.3339774View Description Hide Description
The mutual solubilities and related liquid-liquid equilibria of 60 binary systems of to esters with water are exhaustively and critically reviewed. Reports of experimental determination of solubility that appeared in the primary literature prior to the end of 2007 are compiled. For 26 systems, sufficient data are available to allow critical evaluation. All data are expressed as mass fraction and mole fraction as well as the originally reported units. In addition to the standard evaluation criteria used throughout the Solubility Data Series, a method based on the evaluation of all experimental data for a given series of esters was used.