Volume 43, Issue 2, June 2014
Index of content:
- REGULAR ARTICLES
43(2014); http://dx.doi.org/10.1063/1.4867621View Description Hide Description
Reports of experimental determinations of solubility for 30 ternary systems of C4–C10 alcohols with hydrocarbons and water are exhaustively compiled and critically evaluated. Reports of experimental determination of solubility that appeared in the primary literature prior to the middle of 2012 are included. For seven systems, sufficient data (two or more independent desterminations) for critical evaluation are available. All data are expressed as mass percent and mole fraction as well as the originally reported units. In addition to the standard evaluation criteria used throughout the Solubility Data Series, two additional criteria were used for each of the evaluated systems. These systems include two binary miscibility gaps in the alcohol + water and hydrocarbon + water subsystems. The binary tie lines were compared with the recommended values published previously and with values obtained with a predictive NRTL model.