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IR spectra of water polyaggregates in a nitrogen cryomatrix
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10.1063/1.2746844
/content/aip/journal/ltp/33/8/10.1063/1.2746844
http://aip.metastore.ingenta.com/content/aip/journal/ltp/33/8/10.1063/1.2746844
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Figures

Image of FIG. 1.
FIG. 1.

Variation of the laser interferometer signal during the formation of a cryocondensate of a mixture consisting of 5% water and 95% nitrogen. The condensation temperature is , and the film thickness is .

Image of FIG. 2.
FIG. 2.

IR spectrum of a film of a cryocondensate of a mixture consisting of 5% water and 95% nitrogen. The condensation temperature is , and the film thickness is .

Image of FIG. 3.
FIG. 3.

Evolution of the IR spectrum of a thick film of a cryocondensate consisting of 5% water and 95% nitrogen. The condensation temperature is . The pressure in the chamber during the measurements was . The measurements were performed (1) and (2) after the films were deposited.

Image of FIG. 4.
FIG. 4.

Reflectance of a substrate with different coatings. The IR spectrum of a thick film formed during co-condensation of 5% and 95% on a substrate at and (1); IR spectrum of a film formed from a matrix at after nitrogen has evaporated, the computed film thickness is (2); IR spectrum of a thick film of pure water, formed at and (3).

Image of FIG. 5.
FIG. 5.

Characteristic features of the IR spectra of water molecules in a nitrogen matrix in the range of stretching vibrations. The thick film was formed during co-condensation of 5% and 95% on a substrate at . M—monomers, Dim—dimers, Tr—trimers, Quad—quadromers, Pen—pentamers, Hex—hexamers, Pol—polymers.

Image of FIG. 6.
FIG. 6.

Characteristic features of the IR spectra of water molecules in a nitrogen matrix in the frequency range of bending vibrations. The thick film was formed during co-condensation of 5% and 95% on a substrate at .

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/content/aip/journal/ltp/33/8/10.1063/1.2746844
2007-08-01
2014-04-19
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: IR spectra of water polyaggregates in a nitrogen cryomatrix
http://aip.metastore.ingenta.com/content/aip/journal/ltp/33/8/10.1063/1.2746844
10.1063/1.2746844
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