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Infrared spectroscopy of the organic monolayer sandwiched between a Hg electrode and a Si substrate
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10.1063/1.3422256
/content/aip/journal/rsi/81/5/10.1063/1.3422256
http://aip.metastore.ingenta.com/content/aip/journal/rsi/81/5/10.1063/1.3422256

Figures

Image of FIG. 1.
FIG. 1.

Schematic diagrams of (a) the bird’s-eye view and (b) the cross sectional view of the present IRAS device for a sandwiched monolayer between a Si substrate and a Hg electrode.

Image of FIG. 2.
FIG. 2.

Vibrational spectra for a C18 monolayer on Si(111) by (a) transmission IR with the incidence of the Brewster angle, and (b) IRAS.

Image of FIG. 3.
FIG. 3.

(a) Optical path of IRAS based on the three-phase model with a Si layer. (b) Optical path in transmission measurement. The , , and refer to the dielectric functions, refractive indexes, and extinction coefficients, respectively.

Image of FIG. 4.
FIG. 4.

Difference spectra of the C18 monolayer between the nonbias and certain bias voltages. : the applied bias to the Hg electrode, and I: current. The short bars indicate the position of peaks and dips.

Tables

Generic image for table
Table I.

Assignments for C–H stretching modes of the C18 monolayer on Si(111).

Generic image for table
Table II.

Comparison of noise levels in absorbance.

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/content/aip/journal/rsi/81/5/10.1063/1.3422256
2010-05-12
2014-04-19
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Infrared spectroscopy of the organic monolayer sandwiched between a Hg electrode and a Si substrate
http://aip.metastore.ingenta.com/content/aip/journal/rsi/81/5/10.1063/1.3422256
10.1063/1.3422256
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