- Conference date: 13−17 Jun 1994
- Location: Toronto, Canada
In this paper we shall describe recent experimental studies of line mixing effects observed in various IR vibrational bands of CO2 in a bath of He over a wide range of different physical parameters. We shall show how an ECS (Energy Corrected Sudden) model derived from the IOS (Infinite Order Sudden) formalism of Green (J. Chem. Phys. 90, 3606 (1989)) leads to theoretical predictions in rather good agreement with experiment, whatever the vibrational band considered. We shall rely this result to the ability of the formalism to predict coupling cross‐sections which strongly depend on the vibrational angular momentum
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