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Effects of amine- and pyridine-terminated molecular nanolayers on adhesion at interfaces
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10.1116/1.1856467
/content/avs/journal/jvstb/23/1/10.1116/1.1856467
http://aip.metastore.ingenta.com/content/avs/journal/jvstb/23/1/10.1116/1.1856467

Figures

Image of FIG. 1.
FIG. 1.

Typical load-displacement curves obtained for (solid line) and (dashed line) structures from four-point bend tests. Structures with APTMS show a higher load plateau than those with TMSEP.

Image of FIG. 2.
FIG. 2.

XPS spectra of N obtained from APTMS (solid line) and TMSEP (dashed line) MNLs formed using (a) and (b) solutions.

Image of FIG. 3.
FIG. 3.

Ellipsometry measurement of thickness as a function of APTMS and TMSEP concentration for films formed from (open squares) and solutions (open circles). The theoretical thickness (filled triangles) is shown for reference.

Image of FIG. 4.
FIG. 4.

Interfacial debonding energies of APTMS and TMSEP prepared from 5 and solutions compared with that of the control sample.

Image of FIG. 5.
FIG. 5.

XPS spectra from fracture surfaces of (a) and (b) structures showing N peaks only on the side. Insets show high resolution scans in the vicinity of the N band. Dashed curves correspond to Cu fracture surface and solid lines correspond to fracture surface.

Tables

Generic image for table
TABLE I.

Structure of MNLs used in our study.

Generic image for table
TABLE II.

Equilibrium contact angles for TMSEP and APTMS MNLs formed from solutions of different concentrations.

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/content/avs/journal/jvstb/23/1/10.1116/1.1856467
2005-01-27
2014-04-16
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Effects of amine- and pyridine-terminated molecular nanolayers on adhesion at Cu–SiO2 interfaces
http://aip.metastore.ingenta.com/content/avs/journal/jvstb/23/1/10.1116/1.1856467
10.1116/1.1856467
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