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Surface modification of gold–carbon nanotube nanohybrids under the influence of near-infrared laser exposure
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10.1116/1.4715698
/content/avs/journal/jvstb/30/3/10.1116/1.4715698
http://aip.metastore.ingenta.com/content/avs/journal/jvstb/30/3/10.1116/1.4715698

Figures

Image of FIG. 1.
FIG. 1.

(Color online) Experimental setup outlining the laser path and sample position presented as (a) schematic and (b) digital image.

Image of FIG. 2.
FIG. 2.

(Color online) Functionalization, capture, and labeling process. (1) Condensation of carboxylic acids and amino-modified ssDNA leading to biofunctionalized SWNTs. (2) Capture of csDNA and hybridization with ssDNA into dsDNA on SWNT sidewalls. (3) Addition of GNP labels onto functional thiolated end of dsDNA-SWNTs.

Image of FIG. 3.
FIG. 3.

Transmission electron micrographs demonstrating labeling of biofunctionalized SWNTs with GNPs before and after exposure to NIR. (a) 10 nm, (b) 30 nm, (c) 60 nm, (d) SWNT-GNP10 nm, (e) SWNT-GNP30 nm, (f) SWNT-GNP60 nm, (g) SWNT-GNP10 nm post NIR, (h) SWNT-GNP30 nm post NIR, and (i) SWNT-GNP60 nm post NIR.

Image of FIG. 4.
FIG. 4.

(Color online) Representative heating kinetic profiles (change in temperature over time) for SWNT solutions irradiated with 4.5 W laser for 5 min and monitored during cooling for an additional 5 min.

Image of FIG. 5.
FIG. 5.

(Color online) Overview of the biomolecular functionalization and capture process to form hybrid SWNT-GNP nanostructures, which are further modified upon NIR laser exposure. (1) Binding of biomolecules onto SWNT surface. (2) Hybridization of complementary target binding sequences. (3) Addition of GNPs. (4) Detachment of GNPs via NIR laser exposure.

Tables

Generic image for table
TABLE I.

Summary of surface charge of nanomaterials prior to and after NIR exposure.

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/content/avs/journal/jvstb/30/3/10.1116/1.4715698
2012-05-21
2014-04-25
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Surface modification of gold–carbon nanotube nanohybrids under the influence of near-infrared laser exposure
http://aip.metastore.ingenta.com/content/avs/journal/jvstb/30/3/10.1116/1.4715698
10.1116/1.4715698
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