We present the first study of the

decay of
23Al undertaken with pure samples. The study was motivated by nuclear astrophysics questions. Pure samples of
23Al were obtained from the momentum achromat recoil separator (MARS) of Texas A&M University, collected on a fast tape-transport system, and moved to a shielded location where

and

-

coincidence measurements were made. We deduced

branching ratios and log
ft values for transitions to states in
23Mg, and from them determined unambiguously the spin and parity of the
23Al ground state to be
J
=5/2
+. We discuss how this excludes the large increases in the radiative proton capture cross section for the reaction
22Mg(
p,

)
23Al at astrophysical energies, which were implied by claims that the spin and parity is
J
=1/2
+. The log
ft for the Fermi transition to its isobaric analog state (IAS) in
23Mg is also determined for the first time. This IAS and a state 16 keV below it are observed, well separated in the same experiment for the first time. We can now solve a number of inconsistencies in the literature, exclude strong isospin mixing claimed before, and obtain a new determination of the resonance strength. Both states are resonances in the
22Na(
p,

)
23Mg reaction at energies important in novae. The reactions
22Mg(
p,

)
23Al and
22Na(
p,

)
23Mg have both been suggested as possible candidates for diverting some of the flux in oxygen-neon novae explosions from the
A=22 into the
A=23 mass chain.