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The elusive chemical potential

American Journal of Physics -- April 2001 -- Volume 69, Issue 4, pp. 423-434

Issue Date: April 2001
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KEYWORDS and PACS

Keywords
PACS
  • 01.50.-i
    Communication, education, history, and philosophy Educational aids
  • 05.70.-a
    Statistical physics, thermodynamics, and nonlinear dynamical systems Thermodynamics (see also 64 Equations of state, phase equilibria, and phase transitions, and 65 Thermal properties of condensed matter; for chemical thermodynamics, see 82.60)
  • YEAR: 2001

PUBLICATION DATA

ISSN:
0002-9505 (print)  
Publisher:
AIP is a member of CrossRef AAPT
Ralph Baierlein
Department of Physics and Astronomy, Northern Arizona University, Flagstaff, Arizona 86011-6010
This paper offers some qualitative understanding of the chemical potential, a topic that students invariably find difficult. Three "meanings" for the chemical potential are stated and then supported by analytical development. Two substantial applications—depression of the melting point and batteries—illustrate the chemical potential in action. The origin of the term "chemical potential" has its surprises, and a sketch of the history concludes the paper. ©2001 American Association of Physics Teachers.
History: Received 12 April 2000; accepted 10 October 2000
Permalink: http://dx.doi.org/10.1119/1.1336839

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