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Resonance enhanced multiphoton ionization spectra of CHCl2 and CDCl2 were observed between 355–375 nm via a 2+1 excitation process. Electronic origins tentatively assigned to 3d Rydberg states w...
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Resonance-enhanced multiphoton ionization spectra of SiCl between 430–520 nm

AIP Conf. Proc. -- October 1, 1988 -- Volume 172, pp. 340-342
; doi:10.1063/1.37336

Issue Date: 1 October 1988

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Russell D. Johnson III and Jeffrey W. Hudgens
Chemical Kinetics Division, National Bureau of Standards, Gaithersburg, Maryland 20899
SiCl radical is observed from 430 to 520 nm by resonance enhanced multiphoton ionization. The spectra arise from two photon transitions to the C 2Pir, D 2Sigma+, and E states. Absorption of a third laser photon formed the cation. Both higher vibrations of the C 2Pir state (v[script ']=3–7) and the Si37Cl spectrum of the C 2Pir state are observed. The Si35Cl C 2Pir state vibrations can be fit with constants of omegae=682.7±3.8 cm−1 and omegaexe=3.8±0.5 cm−1.
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KEYWORDS and PACS

Keywords
PACS
  • 33.80.Rv
    Molecular spectra and interactions of molecules with photons Photon interactions with molecules Multiphoton ionization and excitation to highly excited states (e.g., Rydberg states)
  • YEAR: 1988

PUBLICATION DATA

ISSN:
0094-243X (print)  
Publisher:
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