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The electrostatic polarization of ferroelectric liquid crystals: A new interpretation of the triangle-wave technique

Appl. Phys. Lett. 65, 1590 (1994); doi:10.1063/1.112923

Issue Date: 19 September 1994

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J. Ruth, J. V. Selinger, and R. Shashidhar
Center for Bio/Molecular Science and Engineering, Naval Research Laboratory, Code 6900, 4555 Overlook Avenue, SW, Washington, DC 20375-5348
We show that the electrostatic polarization measured in ferroelectric liquid crystals using the standard triangle-wave technique is not the total polarization of the sample, but rather a specific nonlinear component of the total polarization. We present a Landau theory to calculate this nonlinear component explicitly. In the high-temperature limit, above the smectic-A–smectic-C* phase transition, the theory predicts that the observed polarization scales as E3/(TTAC)4, where T is the temperature and E the applied electric field. In the low-temperature limit, the observed polarization approaches the total polarization. These theoretical predictions are consistent with experimental measurements. Applied Physics Letters is copyrighted by The American Institute of Physics.
History: Received 6 May 1994; accepted 11 July 1994
Permalink: http://link.aip.org/link/?APPLAB/65/1590/1
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KEYWORDS and PACS

Keywords
PACS
  • 61.30.-v
    Structure of solids and liquids; crystallography Liquid crystals
  • 77.80.-e
    Dielectrics, piezoelectrics, and ferroelectrics and their properties Ferroelectricity and antiferroelectricity
  • 77.22.Ej
    Dielectrics, piezoelectrics, and ferroelectrics and their properties Dielectric properties of solids and liquids Polarization and depolarization
  • 77.84.Nh
    Dielectrics, piezoelectrics, and ferroelectrics and their properties Dielectric, piezoelectric, and ferroelectric materials Liquids, emulsions, and suspensions; liquid crystals
  • YEAR: 1994

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PUBLICATION DATA

ISSN:
0003-6951 (print)   1077-3118 (online)
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REFERENCES (6)

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  2. K. Miyasato, S. Abe, H. Takezoe, A. Fukuda, and E. Kuze, Jpn. J. Appl. Phys. 22, L661 (1983).
  3. J. Ruth, J. Naciri, and R. Shashidhar, Liq. Cryst. J. Cryst. 16, 883 (1994).
  4. For example, see B. Zeks and R. Blinc, in Ferroelectric Liquid Crystals: Principles, Properties, and Applications, edited by J. W. Goodby et al.(Gordon and Breach, Philadelphia, 1991), p. 365;
  5. R. Blinc, in Phase Transitions in Liquid Crystals, edited by S. Martellucci and A. N. Chester (Plenum, New York, 1992), p. 343.
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  7. J. Naciri, S. Pfeiffer, and R. Shashidhar, Liq. Cryst. 10, 585 (1991).

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