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Simulation of chemical mechanical planarization of copper with molecular dynamics

Appl. Phys. Lett. 81, 1875 (2002); doi:10.1063/1.1505113

Issue Date: 2 September 2002

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Y. Ye
Department of Physics and Astronomy, Microelectronics Research Center and Ames Laboratory, Iowa State University, Ames, Iowa 50011
Center of Analysis and Testing, Wuhan University, Wuhan, People's Republic of China


R. Biswas
Department of Physics and Astronomy, Microelectronics Research Center and Ames Laboratory, Iowa State University, Ames, Iowa 50011

A. Bastawros
Department of Aerospace Engineering and Engineering Mechanics, Iowa State University, Ames, Iowa 50011

A. Chandra
Department of Mechanical Engineering, Iowa State University, Ames, Iowa 50011
With an aim to understanding the fundamental mechanisms underlying chemical mechanical planarization (CMP) of copper, we simulate the nanoscale polishing of a copper surface with molecular dynamics utilizing the embedded atom method. Mechanical abrasion produces rough planarized surfaces with a large chip in front of the abrasive particle, and dislocations in the bulk of the crystal. The addition of chemical dissolution leads to very smooth planarized copper surfaces and considerably smaller frictional forces that prevent the formation of bulk dislocations. This is a first step towards understanding the interplay between mechanistic material abrasion and chemical dissolution in chemical mechanical planarization of copper interconnects. ©2002 American Institute of Physics.
History: Received 14 March 2002; accepted 11 July 2002
Permalink: http://link.aip.org/link/?APPLAB/81/1875/1
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KEYWORDS and PACS

Keywords
PACS
  • 81.65.Ps
    Materials science Surface treatments Polishing, grinding, surface finishing
  • 68.35.Bs
    Surfaces and interfaces; thin films and low-dimensional systems (structure and nonelectronic properties) Solid surfaces and solid-solid interfaces: Structure and energetics Structure of clean surfaces (reconstruction)
  • 64.75.+g
    Equations of state, phase equilibria, and phase transitions Solubility, segregation, and mixing; phase separation
  • 85.40.Ls
    Electronic and magnetic devices; microelectronics Microelectronics: LSI, VLSI, ULSI; integrated circuit fabrication technology Metallization, contacts, interconnects; device isolation
  • 61.72.Lk
    Structure of solids and liquids; crystallography Defects and impurities in crystals; microstructure Linear defects: dislocations, disclinations
  • 62.20.Qp
    Mechanical and acoustical properties of condensed matter Mechanical properties of solids Tribology and hardness
  • YEAR: 2002

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PUBLICATION DATA

ISSN:
0003-6951 (print)   1077-3118 (online)
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REFERENCES (10)

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  2. Several relevant recent articles on this subject appear in Chemical–Mechanical Polishing 2000: Fundamental and Materials Issues, edited by R. K. Singh, R. Bajaj, M. Meuris, and M. Moinpour, Mater. Res. Soc. Symp. Proc. 613, (2000);
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