Applied Physics Letters
Search:
   
 
 
 
Previous Article
Efficient polarized light-emitting diodes utilizing ultrathin photoaddressable alignment layers
We demonstrate that an ultrathin photoaddressable polymer (PAP) layer with a thickness as small as 5 nm can be utilized for the monodomain alignment of thermotropic liquid crystalline polyfluorene. Th...
Next Article
Resolution of photonic crystal superprism
We theoretically investigated the performance of the photonic crystal superprism, that is, the propagating beam quality, the wavelength sensitivity, and the resolution as a narrow band filter at 1.5-&...

Third-order nonlinear optical properties of in-backbone substituted conjugated polymers

Appl. Phys. Lett. 81, 2322 (2002); doi:10.1063/1.1507834

Issue Date: 23 September 2002

You are not logged in to this journal. Log in

U. Gubler, S. Concilio, Ch. Bosshard, I. Biaggio, and P. Günter
Institute of Quantum Electronics, ETH-Hönggerberg, CH-8093 Zürich, Switzerland

R. E. Martin, M. J. Edelmann, J. A. Wytko, and F. Diederich
Laboratorium für Organische Chemie, ETH Hönggerberg, CH-8093 Zürich, Switzerland
We present an alternative approach to tune the third-order nonlinear optical properties of organic molecules by inserting a functional group into the path of the pi-electron conjugation instead of at its ends. We show that this scheme has a beneficial influence on the second-order hyperpolarizability for short molecules, but that in two instances where such molecules were polymerized into longer molecules the overall hyperpolarizability is reduced. ©2002 American Institute of Physics.
History: Received 5 April 2002; accepted 25 July 2002
Permalink: http://link.aip.org/link/?APPLAB/81/2322/1
BUY THIS ARTICLE   (US$24)
Download HTML Download Sectioned HTML Download PDF (50 kB) View Cart

KEYWORDS and PACS

Keywords
PACS
  • 42.65.An
    Optics Nonlinear optics Optical susceptibility, hyperpolarizability
  • 42.70.Jk
    Optics Optical materials Polymers and organics
  • YEAR: 2002

RELATED DATABASES


To view database links for this article,
you need to log in.
To view database links for this article,
you need to log in.

PUBLICATION DATA

ISSN:
0003-6951 (print)   1077-3118 (online)
Publisher:
AIP is a member of CrossRef AIP

REFERENCES (12)

For access to fully linked references, you need to log in. For access to fully linked references, you need to Log in.
  1. U. Gubler, R. Spreiter, C. Bosshard, P. Günter, R. R. Tykwinski, and F. Diederich, Appl. Phys. Lett. 73, 2396 (1998).
  2. C. Bosshard, R. Spreiter, P. Günter, R. R. Tykwinski, M. Schreiber, and F. Diederich, Adv. Mater. 8, 231 (1996).
  3. H. S. Nalwa, Nonlinear Optics of Organic Molecules and Polymers (CRC, New York, 1997).
  4. J. L. Bredas, C. Adant, P. Tackx, A. Persoons, and B. M. Pierce, Chem. Rev. 94, 243 (1994).
  5. M. G. Kuzyk, Opt. Lett. 25, 1183 (2000).
  6. D. Cotter, R. J. Manning, K. J. Blow, A. D. Ellis, A. E. Kelly, D. Nesset, I. D. Phillips, A. J. Poustie, and D. C. Rogers, Science 286, 1523 (1999).
  7. R. E. Martin, U. Gubler, C. Boudon, V. Gramlich, C. Bosshard, J. P. Gisselbrecht, P. Günter, M. Gross, and F. Diederich, Chem. Eur. J. 3, 1505 (1997).
  8. U. Gubler, C. Bosshard, P. Günter, M. Y. Balakina, J. Cornil, J. L. Bredas, R. E. Martin, and F. Diederich, Opt. Lett. 24, 1599 (1999).
  9. R. E. Martin, J. A. Wytko, F. Diederich, C. Boudon, J. P. Gisselbrecht, and M. Gross, Helv. Chim. Acta 82, 1470 (1999).
  10. P. Siemsen, U. Gubler, C. Bosshard, P. Günter, and F. Diederich, Chem. Eur. J. 7, 1333 (2001).
  11. U. Gubler and C. Bosshard, Phys. Rev. B 61, 10702 (2000).
  12. Details of the polymerization and full characterization of the AB-type polymers will be decribed elsewhere.

CITING ARTICLES

For access to citing articles, you need to log in.
For access to citing articles, you need to Log in.