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Stimulated Stokes downconversion in liquid and solid parahydrogen

Appl. Phys. Lett. 82, 1350 (2003); doi:10.1063/1.1556560

Issue Date: 3 March 2003

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B. J. McCall, A. J. Huneycutt, and R. J. Saykally
Department of Chemistry, University of California at Berkeley, Berkeley, California 94720

C. M. Lindsay and T. Oka
Department of Chemistry, University of Chicago, Chicago, Illinois 60637

M. Fushitani, Y. Miyamoto, and T. Momose
Division of Chemistry, Graduate School of Science, Kyoto University, Kyoto 606-8502, Japan
We report the results of our preliminary investigations into the suitability of condensed-phase parahydrogen as a Raman-shifting medium for infrared cavity ringdown laser absorption spectroscopy. We have observed the conversion of ~10-ns pulses of 532-nm radiation into first-, second-, and third-order vibrational Stokes radiation in bulk liquid and solid parahydrogen after a single 11-cm pass. Unexpectedly, we find that liquid H2 yields more efficient conversion than solid H2 with certain focal geometries, and that in the case of the solid, a collimated or loosely focused pump geometry is more efficient than a tight focus. ©2003 American Institute of Physics.
History: Received 28 October 2002; accepted 4 January 2003
Permalink: http://link.aip.org/link/?APPLAB/82/1350/1
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KEYWORDS and PACS

Keywords
PACS
  • 42.65.Ky
    Optical frequency conversion; optical harmonic generation, including higher-order harmonic generation
  • 42.65.Dr
    Stimulated Raman scattering; CARS
  • 42.60.By
    Design of specific laser systems
  • 42.55.Ye
    Raman lasers
  • 67.80.-s
    Solid helium and related quantum crystals
  • 78.30.Cp
    Infrared and Raman spectra in liquids
  • 78.30.Hv
    Infrared and Raman spectra in nonmetallic inorganics excluding elemental, II-VI and III-V semiconductors and fullerenes
  • YEAR: 2003

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PUBLICATION DATA

ISSN:
0003-6951 (print)   1077-3118 (online)
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REFERENCES (10)

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