Direct and highly sensitive measurement of defect-related absorption in amorphous silicon thin films by cavity ringdown spectroscopy
Appl. Phys. Lett. 84, 3079 (2004); doi:10.1063/1.1713047
Issue Date: 19 April 2004
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Cavity ringdown spectroscopy has been applied to hydrogenated amorphous silicon (a-Si:H) showing that this fully optical method is suited for the detection of defect-related absorption in thin films with a minimal detectable absorption of 1×106 per laser pulse and without the need for a calibration procedure. Absolute absorption coefficient spectra for photon energies between 0.7 and 1.7 eV have been obtained for thin a-Si:H films (498 nm) revealing a different spectral dependence for defects located in the bulk and in the surface/interface region of a-Si:H. ©2004 American Institute of Physics.
| History: | Received 17 November 2003; accepted 25 February 2004 |
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KEYWORDS and PACS
silicon,
hydrogen,
elemental semiconductors,
amorphous semiconductors,
semiconductor thin films,
absorption coefficients,
sensitivity,
optical losses
- 78.66.Jg
Optical properties of amorphous semiconductors; glasses (thin films) - 78.66.Db
Optical properties of elemental semiconductors and insulators (thin films) - 78.20.Ci
Optical constants including refractive index, complex dielectric constant, absorption, reflection and transmission coefficients, emissivity - YEAR: 2004
RELATED DATABASES
PUBLICATION DATA
0003-6951 (print)
1077-3118 (online)
REFERENCES (19)
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- R. A. Street, Hydrogenated Amorphous Silicon (Cambridge University Press, Cambridge, 2002).
- W. B. Jackson, N. M. Amer, A. C. Boccara, and D. Forunier,
Appl. Opt. 20, 1333 (1981) . - M. Van
ek, J. Ko
ka, A. Poruba, and A. Fejfar, J. Appl. Phys. 78, 6203 (1995).
- Cavity-Ringdown Spectroscopy: An Ultratrace Absorption Measurement Technique, edited by K. W. Busch and M. A Busch (American Chemical Society, Washington, DC, 1999).
- A. O'Keefe and D. A. G. Deacon, Rev. Sci. Instrum. 59, 2544 (1988).
- R. Engeln, G. Berden, E. van den Berg, and G. Meijer, J. Chem. Phys. 107, 4458 (1997)
- R. Engeln, G. von Helden, A. J. A. van Roij, and G. Meijer,
Chem. Phys. Lett. 110, 2732 (1999) . - G. A. Marcus and H. A. Schwettman,
Appl. Opt. 41, 5167 (2002) . - D. Kleine, J. Lauterbach, K. Kleinermanns, and P. Hering,
Appl. Phys. B: Lasers Opt. 72, 249 (2001) . - S. L. Logunov,
Appl. Opt. 40, 1570 (2001) . - A. H. M. Smets, J. H van Helden, and M. C. M. van de Sanden,
J. Non-Cryst. Solids 299302, 610 (2002) . - A. C. R. Pipino, Phys. Rev. Lett. 83, 3093 (1999).
- M. D. Wheeler, S. M. Newman, A. J. Orr-Ewing, and M. N. R. Ashfold,
J. Chem. Soc., Faraday Trans. 94, 337 (1998) . - I. M. P. Aarts, B. Hoex, W. M. M. Kessels, A. H. M. Smets, R. Engeln, and M. C. M. van de Sanden (unpublished).
- P. Beckman and A. Spizzichino, The Scattering of Electromagnetic Waves from Rough Surfaces (Pergamon, Oxford, 1963).
- The influence of a nonuniform distribution of absorbers within the film has been neglected here. It can be shown that from the amplitude variations within the interference pattern, as observed in the 1031 nm thick a-Si:H film, it is possible to deduce that a higher number of defects exists at the interface and/or surface of the a-Si:H film (see also Ref. 17).
- A. Asano and M. Stutzmann, J. Appl. Phys. 70, 5025 (1991).
- W. B. Jackson, D. K. Biegelsen, R. J. Nemanich, and J. C. Knights, Appl. Phys. Lett. 42, 105 (1983).
- I. M. P. Aarts, M. C. M. van de Sanden, W. M. M. Kessels, J. Non-Cryst. Solids (to be published).







