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Effects of ferromagnetic nanowires on singlet and triplet exciton fractions in fluorescent and phosphorescent organic semiconductors

Appl. Phys. Lett. 88, 022114 (2006); doi:10.1063/1.2162801

Published 12 January 2006

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Bin Hu and Yue Wu
Department of Materials Science and Engineering, University of Tennessee, Knoxville, Tennessee 37996

Zongtao Zhang and Sheng Dai
Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831

Jian Shen
Condensed Matter Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831
We report a magnetic field-dependent electroluminescence (EL) induced by ferromagnetic Co53Pt47 nanowires in fluorescent conjugated polymer poly[2-methoxy-5-(2[prime]-ethylhexyloxy)-1,4-phenylenevinylene] and phosphorescent iridium-complex Ir(ppy)3 molecules. The photoluminescence and EL studies indicate that the dispersed CoPt nanowires increase the singlet-to-triplet exciton ratio in organic semiconductors, suggesting that the spin-polarized holes were injected into the organic molecules from the CoPt nanowires under electrical excitation. Therefore, the use of ferromagnetic nanomaterials demonstrates a pathway to tune the optoelectronic properties that are related to singlet and triplet states in organic semiconducting materials. ©2006 American Institute of Physics
History: Received 12 September 2005; accepted 24 November 2005; published 12 January 2006
Permalink: http://link.aip.org/link/?APPLAB/88/022114/1
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KEYWORDS and PACS

Keywords
PACS
  • 78.66.Qn
    Optical properties of polymers; organic compounds (thin films)
  • 73.40.Ns
    Electrical properties of metal–nonmetal contacts
  • 78.60.Fi
    Electroluminescence (condensed matter)
  • 78.55.Kz
    Photoluminescence in solid organic materials
  • 71.35.-y
    Excitons and related phenomena
  • YEAR: 2006

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0003-6951 (print)   1077-3118 (online)
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