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Atomic-resolution study of Mn tetramer clusters using scanning tunneling microscopy

Appl. Phys. Lett. 88, 173101 (2006); doi:10.1063/1.2197316

Published 24 April 2006

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Rong Yang, Haiqiang Yang, and Arthur R. Smith
Nanoscale and Quantum Phenomena Institute, Department of Physics and Astronomy, Ohio University, Athens, Ohio 45701
A manganese nitride surface containing a well-ordered array of MnN-bonded manganese clusters is investigated. The clusters are composed of a quadrant array of Mn atoms forming a tetramer. Scanning tunneling microscopy is used to image and resolve the clusters into their constituent atoms and their structure and arrangement is presented. The Mn–Mn and Mn–N bond lengths are estimated from the experimental data and compared with theoretical predictions by Rao and Jena [Phys. Rev. Lett. 89, 185504 (2002)] for free, N-doped Mn clusters. The possible effect of the bond lengths on the magnetic properties of the clusters is discussed. ©2006 American Institute of Physics
History: Received 28 November 2005; accepted 8 March 2006; published 24 April 2006
Permalink: http://link.aip.org/link/?APPLAB/88/173101/1
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KEYWORDS and PACS

Keywords
PACS
  • 61.46.Bc
    Clusters
  • 75.50.Ee
    Antiferromagnetics
  • 75.50.Tt
    Fine-particle magnetic systems; nanocrystalline materials
  • 68.37.Ef
    Scanning tunneling microscopy of surfaces, interfaces and thin films including chemistry induced with STM
  • YEAR: 2006

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ISSN:
0003-6951 (print)   1077-3118 (online)
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