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Oxidation-enhanced interdiffusion in Si1−xGex/Si1−yGey superlattices
The effects of Si surface oxidation on Si–Ge interdiffusion in epitaxial heterostructures are presented. Single crystal Si1−xGex/Si1−yGey superlattices, with a nominal Ge composition...

Chemical routes to Ge/Si(100) structures for low temperature Si-based semiconductor applications

Appl. Phys. Lett. 90, 082108 (2007); doi:10.1063/1.2437098

Published 23 February 2007

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M. A. Wistey, Y.-Y. Fang, J. Tolle, A. V. G. Chizmeshya, and J. Kouvetakis
Department of Chemistry and Biochemistry, Arizona State University, Tempe, Arizona 85287
The authors describe very low temperature (350–420  °C) growth of atomically smooth Ge films (0.2–0.4  nm roughness) directly on Si(100) via gas-source molecular beam epitaxy. A carefully tuned admixture of (GeH3)2CH2, possessing unique pseudosurfactant properties, and conventional Ge2H6 provides unprecedented control of film microstructure, morphology, and composition. Formation of edge dislocations at the interface ensures growth of virtually relaxed monocrystalline Ge films (~40–1000  nm thick) with a threading dislocation density less than 105  cm−2 as determined by etch pit measurements. Secondary ion mass spectroscopy showed no measurable carbon incorporation indicating that C desorbs as CH4, consistent with calculated chemisorption energies. ©2007 American Institute of Physics
History: Received 16 November 2006; accepted 3 January 2007; published 23 February 2007
Permalink: http://link.aip.org/link/?APPLAB/90/082108/1
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KEYWORDS and PACS

Keywords
PACS
  • 81.15.Hi
    Molecular, atomic, ion, and chemical beam epitaxy
  • 68.55.Ac
    Thin film nucleation and growth: microscopic aspects
  • 79.20.Rf
    Atomic, molecular, and ion beam impact and interactions with surfaces
  • 82.80.Ms
    Mass spectrometry (chemical analysis) including SIMS, multiphoton ionization and resonance ionization mass spectrometry, MALDI
  • 68.43.Mn
    Adsorption/desorption kinetics
  • 61.72.Hh
    Indirect evidence of dislocations and other defects including resistivity, slip, creep, strains, internal friction, EPR, NMR, etc.
  • YEAR: 2007

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PUBLICATION DATA

ISSN:
0003-6951 (print)   1077-3118 (online)
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REFERENCES (8)

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