Development of nonaqueous polymer gels that exhibit broad temperature performance
Appl. Phys. Lett. 91, 061929 (2007); doi:10.1063/1.2769938
Published 10 August 2007
You are not logged in to this journal. Log in
While significant work has focused on aqueous hydrogels for biotechnology applications, hydrogels suffer from a limited operating temperature range due to the moderate freezing point and high volatility of water. In this work, a nonaqueous, chemically cross-linked polybutadiene gel has been designed which exhibits stable properties over a temperature range of −60–70 °C. A combination of rheology, neutron scattering, and tack adhesion testing was utilized to characterize the gel properties. The methodology employed to design the polybutadiene gel can be generalized to a variety of gel materials and applications.
©2007 American Institute of Physics
| History: | Received 22 May 2007; accepted 19 July 2007; published 10 August 2007 |
| Permalink: |
http://link.aip.org/link/?APPLAB/91/061929/1 |
REFERENCES (17)
For access to fully linked references, you need to log in.
For access to fully linked references, you need to Log in.
- P. J. Flory, Principles of Polymer Chemistry (Cornell University, Ithaca, NY, 1953), Vol. 1, p. 576.
- T. Tanaka, Phys. Rev. A 17, 763 (1978).
- M. V. Sussman and A. Katchalsky,
Science 167, 45 (1970) . - I. C. Kwon, Y. H. Bae, and S. W. Kim,
Nature (London) 354, 291 (1991) . - C. Gallegos and J. M. Franco,
Curr. Opin. Colloid Interface Sci. 4, 288 (1999) . - J. L. Lenhart, W.-Q. Sun, and G. F. Payne,
Chem. Eng. Sci. 52, 645 (1997) . - D. J. Beebe, J. S. Moore, J. M. Baure, Q. Yu, R. H. Liu, C. Devadoss, and B.-H. Jo,
Nature (London) 404, 588 (2000) . - M. Otake, Y. Kagami, M. Inaba, and H. Inoue, Robotics Autom. Sys. 40, 185 (2002).
- G. Wang, K. Kuroda, T. Enoki, A. Grosberg, S. Masamune, T. Oya, Y. Takeoka, and T. Tanaka,
Proc. Natl. Acad. Sci. U.S.A. 97, 9861 (2000) . - J. M. Weissman, H. B. Sunkara, A. S. Tse, and S. A. Asher,
Science 274, 959 (1996) . - J. H. Holtz and S. A. Asher,
Nature (London) 389, 829 (1997) . - H. H. Al-Sharji, C. A. Grattoni, R. A. Dawe, and R. W. Zimmerman,
Oil Gas Sci. Technol. 56, 145 (2001) . - Y. Hirokawa and T. Tanaka, J. Chem. Phys. 81, 6379 (1984).
- T. G. Park,
Biomaterials 20, 517 (1999) . - D. Schmaljohann, J. Oswald, B. Jorgensen, M. Nitschke, D. Beyerlein, and C. Werner,
Biomacromolecules 4, 1733 (2003) . - MA5 and R45 were obtained from Sartomer (see Sartomer product sheets at www.sartomer.com).
- J. L. Lenhart and P. J. Cole,
J. Adhes. 82, 945 (2006) .







