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Development of nonaqueous polymer gels that exhibit broad temperature performance

Appl. Phys. Lett. 91, 061929 (2007); doi:10.1063/1.2769938

Published 10 August 2007

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Joseph L. Lenhart
Sandia National Laboratories, Albuquerque, New Mexico 87185

Phillip J. Cole
Sandia National Laboratories, Albuquerque, New Mexico 87185

Burcu Unal and Ronald Hedden
Materials Science and Engineering Department, Pennsylvania State University, University Park, Pennsylvania 16802
While significant work has focused on aqueous hydrogels for biotechnology applications, hydrogels suffer from a limited operating temperature range due to the moderate freezing point and high volatility of water. In this work, a nonaqueous, chemically cross-linked polybutadiene gel has been designed which exhibits stable properties over a temperature range of −60–70  °C. A combination of rheology, neutron scattering, and tack adhesion testing was utilized to characterize the gel properties. The methodology employed to design the polybutadiene gel can be generalized to a variety of gel materials and applications. ©2007 American Institute of Physics
History: Received 22 May 2007; accepted 19 July 2007; published 10 August 2007
Permalink: http://link.aip.org/link/?APPLAB/91/061929/1
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KEYWORDS and PACS

Keywords
PACS
  • 82.70.Gg
    Gels and sols
  • 83.80.Kn
    Physical gels and microgels (rheology)
  • 83.80.Rs
    Polymer solutions (rheology)
  • 61.25.Hq
    Structure of macromolecular and polymer solutions, and polymer melts; swelling
  • 81.20.-n
    Methods of materials synthesis and materials processing
  • YEAR: 2007

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PUBLICATION DATA

ISSN:
0003-6951 (print)   1077-3118 (online)
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