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Standoff photoacoustic spectroscopy

Appl. Phys. Lett. 92, 234102 (2008); doi:10.1063/1.2945288

Published 12 June 2008

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C. W. Van Neste,1 L. R. Senesac,1,2 and T. Thundat1,2
1Biosciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA
2Department of Physics, University of Tennessee, Knoxville, Tennessee 37996, USA

Here, we demonstrate a variation of photoacoustic spectroscopy that can be used for obtaining spectroscopic information of surface adsorbed chemicals in a standoff fashion. Pulsed light scattered from a target excites an acoustic resonator and the variation of the resonance amplitude as a function of illumination wavelength yields a representation of the absorption spectrum of the target. We report sensitive and selective detection of surface adsorbed compounds such as tributyl phosphate and residues of explosives such as trinitrotoluene at standoff distances ranging from 0.5–20  m, with a detection limit on the order of 100  ng/cm2. ©2008 American Institute of Physics
History: Received 1 May 2008; accepted 20 May 2008; published 12 June 2008
Permalink: http://link.aip.org/link/?APPLAB/92/234102/1
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KEYWORDS and PACS

Keywords
PACS
  • 43.58.Kr
    Spectrum and frequency analyzers and filters; acoustical and electrical oscillographs; photoacoustic spectrometers; acoustical delay lines and resonators
  • 82.80.Kq
    Energy-conversion spectroscopic methods of chemical analysis
  • 78.20.Hp
    Piezo-, elasto-, and acoustooptical effects (bulk materials/thin films)
  • 62.65.+k
    Acoustical properties of solids
  • 68.43.-h
    Chemisorption/physisorption: adsorbates on surfaces
  • YEAR: 2008

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PUBLICATION DATA

ISSN:
0003-6951 (print)   1077-3118 (online)
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REFERENCES (12)

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