Standoff photoacoustic spectroscopy
Appl. Phys. Lett. 92, 234102 (2008); doi:10.1063/1.2945288
Published 12 June 2008
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Here, we demonstrate a variation of photoacoustic spectroscopy that can be used for obtaining spectroscopic information of surface adsorbed chemicals in a standoff fashion. Pulsed light scattered from a target excites an acoustic resonator and the variation of the resonance amplitude as a function of illumination wavelength yields a representation of the absorption spectrum of the target. We report sensitive and selective detection of surface adsorbed compounds such as tributyl phosphate and residues of explosives such as trinitrotoluene at standoff distances ranging from 0.5–20 m, with a detection limit on the order of 100 ng/cm2.
©2008 American Institute of Physics
| History: | Received 1 May 2008; accepted 20 May 2008; published 12 June 2008 |
| Permalink: |
http://link.aip.org/link/?APPLAB/92/234102/1 |
KEYWORDS and PACS
acoustic resonators,
adsorbed layers,
explosives,
organic compounds,
photoacoustic spectra,
photoacoustic spectroscopy
- 43.58.Kr
Spectrum and frequency analyzers and filters; acoustical and electrical oscillographs; photoacoustic spectrometers; acoustical delay lines and resonators - 82.80.Kq
Energy-conversion spectroscopic methods of chemical analysis - 78.20.Hp
Piezo-, elasto-, and acoustooptical effects (bulk materials/thin films) - 62.65.+k
Acoustical properties of solids - 68.43.-h
Chemisorption/physisorption: adsorbates on surfaces - YEAR: 2008
RELATED DATABASES
PUBLICATION DATA
0003-6951 (print)
1077-3118 (online)
REFERENCES (12)
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