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The crystal structure of the group of compounds with the general formula M2 + " align="middle"/>M2+(Hal)4, where the magnetic ion may be Mn2+, Ni2+, or Cu2+ for instance, strongly suggests the possibi...
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A Localized-Electron to Collective-Electron Transition in the System (La, Sr)CoO3

J. Appl. Phys. 39, 1209 (1968); doi:10.1063/1.1656227

Issue Date: 1 February 1968

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P. M. Raccah and J. B. Goodenough
Lincoln Laboratory, Massachusetts Institute of Technology, Lexington, Massachusetts
Crystallographic, magnetic, and electrical studies of the system La1−xSrxCoO3.00±0.01 for 0<=x<=0.5 give indirect evidence for the presence of chemical inhomogeneities separating strontium-free regions, where localized ``3d'' electrons occur at thermally excited high-spin Co3+ ions, from strontium-rich regions, where the ``3d'' electrons are collective and give ferromagnetism at low temperatures. These different regions occur within the same rhombohedral perovskite crystal and appear to represent two different electronic phases within the same crystallographic phase. A schematic band model for the ferromagnetic phase is presented. ©1968 The American Institute of Physics
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0021-8979 (print)   1089-7550 (online)
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REFERENCES (5)

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  1. P. M. Raccah and J. B. Goodenough, Phys. Rev. 155, 932 (1967).
  2. J. B. Goodenough, J. Phys. Chem. Solids 6, 287 (1958).
  3. G. H. Jonker and J. H. Van Santen, Physica 19, 120 (1953).
  4. J. B. Goodenough, J. Appl. Phys. 39, 403 (1968), this issue.
  5. J. B. Goodenough, J. Appl. Phys. 37, 1415 (1966).

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