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High pressure studies of Ge using synchrotron radiation

J. Appl. Phys. 54, 3609 (1983); doi:10.1063/1.332434

Issue Date: June 1983

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S. B. Qadri, E. F. Skelton, and A. W. Webb
Stanford Synchrotron Radiation Laboratory, Stanford University, Stanford, California 94305
Compressibility studies have been carried out on Ge–I (diamond-cubic structure) to 12.0 GPa; the results are in very good agreement with previous work. We confirm the recent report of a substantial lowering of the Ge I–II transition pressure in a nonhydrostatic pressure environment. We observe the Ge–II (200)-peak at 10.5±0.2 GPa in a more hydrostatic pressure environment and as low as 6.7 GPa when shear stresses are present. On release of pressure from above 11 GPa, we find that Ge–II converts predominantly into Ge–III when Ge–I and shear stresses are present and completely into Ge–III in the absence of Ge–I in a more hydrostatic pressure environment. This is contrary to what had been previously presumed. Journal of Applied Physics is copyrighted by The American Institute of Physics.
History: Received 8 October 1982; accepted 16 February 1983
Permalink: http://link.aip.org/link/?JAPIAU/54/3609/1
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KEYWORDS and PACS

Keywords
PACS
  • 64.70.Kb
    Equations of state, phase equilibria, and phase transitions Phase equilibria, phase transitions, and critical points of specific substances Solidsolid transitions
  • 61.55.Fe
    Structure of liquids and solids; crystallography Specific structures of elements and alloys Metallic elements
  • 62.50.+p
    Mechanical and acoustical properties of condensed matter High-pressure and shock-wave effects in solids
  • 62.20.Dc
    Mechanical and acoustical properties of condensed matter Mechanical properties of solids (related to microscopic structure) Elastic constants
  • YEAR: 1983

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PUBLICATION DATA

ISSN:
0021-8979 (print)   1089-7550 (online)
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