The effect of hydrogen treatment on damaged and undamaged metal-insulator-semiconductor solar cells
J. Appl. Phys. 70, 259 (1991); doi:10.1063/1.350321
Issue Date: 1 July 1991
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A metal-insulator-semiconductor structure was used to study the effect of hydrogen plasma treatment of solar cells. Cells were fabricated on single-crystal p-type silicon and treated in hydrogen plasma for different exposure times. This causes a noticeable drop in the photocurrent and density of charge carriers with exposure time. This in turn leads to a drop in the solar cell efficiency. Other cells were fabricated on damaged p-type silicon, where dislocations were created by lapping the silicon surface. Such a procedure simulates controllably the effect of dislocations and grain boundaries. The damaged silicon was then exposed to hydrogen plasma and an overall improvement in the performance of the solar cell was found. However over-exposure led to degradation as with single-crystal material. It is concluded that hydrogen plasma exposure has both beneficial and degrading effects. It improves solar cell characteristics when they have been degraded by dislocations, but it degrades cells by interacting with accepters in the p-silicon. Further studies are needed to attain the best compromise and to optimize solar cells made from low quality silicon.
Journal of Applied Physics is copyrighted by The American Institute of Physics.
| History: | Received 29 November 1990; accepted 25 March 1991 |
| Permalink: |
http://link.aip.org/link/?JAPIAU/70/259/1 |
KEYWORDS and PACS
SILICON SOLAR CELLS,
DAMAGE,
HYDROGENATION,
FABRICATION,
PERFORMANCE,
PLASMA,
EFFICIENCY,
DISLOCATIONS,
GRAIN BOUNDARIES,
PASSIVATION
- 73.20.Hb
Electronic structure and electrical properties of surfaces, interfaces, and thin films Surface and interface electron states Impurity and defect levels; energy states of adsorbed species - 72.20.Ht
Electronic transport in condensed matter Conductivity phenomena in semiconductors and insulators High-field and nonlinear effects - 84.60.Jt
Electromagnetic technology Direct energy conversion and energy storage Solar cells and arrays - YEAR: 1990-91
PUBLICATION DATA
0021-8979 (print)
1089-7550 (online)
REFERENCES (28)
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- M. Capizzi and A. Mittiga, Physica 146B, 19 (1987).
- P. H. Robinson and R. V. D'Aiello, Appl. Phys. Lett. 39, 63 (1981).
- A. J. Tavendale and A. A. Williams, Appl. Phys. Lett. 48, 590 (1986).
- S. J. Pearton, J. W. Corbett, and T. S. Shi,
Appl. Phys. A 43, 153 (1987 ). - K. J. Chang and D. J. Chadi, Phys. Rev. Lett. 60, 1422 (1988).
- J. Kassobobov, D. Dimitrov, and A. Grueva,
Solid-State Electron. 31, 49 (1988 ). - K. Schmalz, R. Krause, H. Richter, and K. Tittelbach-Hermrich,
Phys. Status Solidi A 100, K123 (1987 ). - A. Rohatgi, D. L. Meier, P. Rai-Choudhury, S. J. Fonash, and R. Singh, J. Appl. Phys. 59, 4167 (1986).
- A. Ourmazd, D. W. Taylor, J. A. Rentschler, and F. Bevk, Phys. Rev. Lett. 59, 213 (1987).
- L. L. Kazmerski, A. J. Nelson, and R. G. Dhere,
J. Vac. Sci. Technol. A 5, 1994 (1987 ). - C. T. Sah, J. Y. C. Sun, and J. J. T. Tzou, Appl. Phys. Lett. 43, 204 (1983).
- N. M. Johnson, C. Herring, and D. J. Chadi, Phys. Rev. Lett. 56, 769 (1986).
- R. J. Van Overstraeten and R. P. Mertens, Physics Technology and Use of Photovoltaics (Adam Hilger, London, 1986).
- C. H. Seager, D. S. Ginley, and J. D. Zook, Appl. Phys. Lett. 36, 831 (1980).
- L. Ammor and S. Marionuzzi,
Solid-State Electron. 29, 1 (1986 ). - S. Marionuzzi, L. Ammor, M. Sebbar, and G. Mathian, 6th E. C. Photovoltaic Solar Energy Conference, p. 1026, 1985.
- X. C. Mu, S. J. Fonash, B. Y. Yang, L. Vedam, A. Rohtgi, and J. Rieger, J. Appl. Phys. 58, 4282 (1985).
- C. H. Seager and D. S. Ginley, J. Appl. Phys. 52, 1050 (1981).
- C. Dube, J. I. Hanoka, and D. B. Sandstom, Appl. Phys. Lett. 44, 425 (1984).
- J. C. Muller, Y. Ababou, A. Barhdadi, E. Courcelle, S. Unamuno, D. Salles, and P. Siffert,
Solar Cells 17, 201 (1986 ). - V. J. Rao, W. A. Anderson, and F. Kai, Grain Boundary in Semiconductors (Elsevier, New York, 1982), p. 229.
- W. M. R. Divigalpitiya and S. R. Morrison, J. Appl. Phys. 60, 406 (1986).
- A. L. Fahrenbruch and R. H. Bube, Fundamentals of Solar Cells (Academic, New York, 1983).
- N. M. Johnson, Phys. Rev. B 31, 5525 (1985).
- S. R. Morrison, The Chemical Physics of Surfaces (Plenum, New York, 1977).
- J. W. Corbett, J. L. Lindstrom, S. J. Pearton, and A. J. Tavendale,
Solar Cells 24, 127 (1988 ). - L. Sardi, S. Pidatella, and G. Figari, J de Phys., colloque C1, Suppl. 43, 125 (1982).
- J. D. Joannopoulos and G. Lucovsky, eds. Topics in Applied Physics (Springer, Berlin, 1984), Vol. 56, p. 51.








