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Trapping of Ce electrons in band gap and room temperature ferromagnetism of Ce4+ doped ZnO nanowires

J. Appl. Phys. 106, 083515 (2009); doi:10.1063/1.3245325

Published 26 October 2009

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Javed Iqbal,1 Xiaofang Liu,1 Huichao Zhu,2 Chongchao Pan,1 Yong Zhang,3 Dapeng Yu,2 and Ronghai Yu1
1Laboratory of Advanced Materials, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, China
2State Key Laboratory for Mesoscopic Physics and Electron Microscopy Laboratory, School of Physics, Peking University, Beijing 100871, China
3Center for Materials Science and Engineering, Massachusetts Institute of Technology (MIT), Cambridge, Massachusetts 02139-4307, USA

Rare-earth (RE) metal doped ZnO nanowires have been fabricated through a simple, quick, and versatile low temperature soft chemical method. The average length and diameter of nanowires lie in range of 5  µm and 60  nm, respectively. Raman and x-ray photoelectron spectroscopy studies demonstrate that Ce has 4+ oxidation state and successfully substitutes Zn up to 2.5% into ZnO single phase wurtzite structure. Doping of Ce shows a remarkably prominent large redshift of 22  nm in the UV region of the band gap, with an increase in the intensity of green emission band due to charge transfer of Ce4+ dopant. In addition, it has been interestingly found that RE (Ce) doped ZnO nanowires exhibit room temperature ferromagnetism, which makes them potential for spintronic devices with excellent optical characteristics. ©2009 American Institute of Physics
History: Received 4 April 2009; accepted 13 September 2009; published 26 October 2009
Permalink: http://link.aip.org/link/?JAPIAU/106/083515/1
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KEYWORDS and PACS

Keywords
PACS
  • 72.20.Jv
    Charge carriers: generation, recombination, lifetime, and trapping (semiconductors/insulators)
  • 73.21.Hb
    Quantum wires (electron states/collective excitations)
  • 75.50.Dd
    Nonmetallic ferromagnetic materials
  • 79.60.Jv
    Photoelectron spectra of interfaces; heterostructures; nanostructures
  • 75.50.Pp
    Magnetic semiconductors
  • YEAR: 2009

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ISSN:
0021-8979 (print)   1089-7550 (online)
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