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Technique for the Electrolytic Production of H2H2O
A detailed description of a method of preparing heavy water in quantity is given and yields obtained over a period of months reported.

The Derivation of Equations for Regular Solutions

J. Chem. Phys. 1, 817 (1933); doi:10.1063/1.1749250

Issue Date: December 1933

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J. H. Hildebrand and S. E. Wood
Department of Chemistry, University of California
The probability function of Menke has been used as a basis for a statistical treatment of the intermolecular potentials in solutions of symmetrical molecules for which the entropy of mixing is the same as for an ideal solution of the same composition. The resulting expressions enable calculations to be made of the departure of iodine solutions from the ideal solution laws which agree satisfactorily with the observed departures. The Journal of Chemical Physics is copyrighted by The American Institute of Physics.
History: Received September 27, 1933
Permalink: http://link.aip.org/link/?JCPSA6/1/817/1
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ISSN:
0021-9606 (print)   1089-7690 (online)
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REFERENCES (9)
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  1. J. H. Hildebrand, J. Am. Chem. Soc. 51, 66 (1929);
  2. also Proc. Nat. Acad. Sci. 13, 267 (1927).
  3. Cf. M. v. Schmoluchowski, Ann. d. Physik [4] 25, 205 (1908);
  4. A. Einstein, ibid. 33, 1275 (1910);
  5. Wo. Ostwald, ibid. 36, 848 (1911).
  6. J. J. van Laar, Zeits. f. Physik. Chemie A137, 421 (1928).
  7. Heitler, Ann. d. Physik [4] 80, 630 (1928).
  8. Cf. also J. H. Hildebrand and E. J. Salstrom, J. Am. Chem. Soc. 54, 4257 (1932).
  9. (a) H. Menke, Phys. Zeits. 33, 593 (1932);
  10. cf. further, (b) O. Kratky, ibid. 34, 482 (1933).
  11. F. London, Zeits. f. Physik 63, 245 (1930).
  12. J. H. Hildebrand, Phys. Rev. 34, 984 (1929).
  13. Geo. Scatchard, Chem. Rev. 8, 321 (1931).
  14. J. H. Hildebrand and C. A. Jenks, J. Am. Chem. Soc. 42, 2080 (1920);
  15. G. R. Negishi, L. H. Donnally and J. H. Hildebrand, ibid. Nov. (1933);
  16. cf. also reference 1.

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