Scattering of Low-Energy H— Ions in Helium, Neon, and Argon
J. Chem. Phys. 26, 1446 (1957); doi:10.1063/1.1743562
Issue Date: June 1957
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Elastic and inelastic cross sections have been measured for the scattering of H— ions in helium, neon, and argon gases, at incident ion energies in the range 5 ev to 350 ev. One term interaction potentials of the form V=—K/rn were calculated from the low-energy elastic cross sections. These potentials were: for H— and He, V=—2.90/r3.01 ev for r=1.30 A to 1.90 A; for H— and Ne, V=—4.17/r2.80 ev for r=1.00 A to 1.78 A; and for H— and A, V=—7.82/r3.40 ev for r=1.23 A to 2.12 A. The observed inelastic cross sections are interpreted as cross sections for electron detachment from H—; they show a similar behavior with ion energy W in the three cases, appearing at W between 0 and 5 ev, rising rapidly to W=40 ev, and then rising very slowly to W=350 ev. Evidence was found for positive ion formation in H— collisions with Ne and A atoms at ion energies above 100 ev.
The Journal of Chemical Physics is copyrighted by The American Institute of Physics.
| History: | Received October 22, 1956 |
| Permalink: |
http://link.aip.org/link/?JCPSA6/26/1446/1 |
PUBLICATION DATA
0021-9606 (print)
1089-7690 (online)
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