Noncombinatorial Method for Determining the Entropy of Lattices
The composition law of information theory is considered in connection with lattice statistics. By the use of this law it is found that many of the standard exact and approximate results (exact solutio...
The composition law of information theory is considered in connection with lattice statistics. By the use of this law it is found that many of the standard exact and approximate results (exact solutio...
ESR Evidence on Trapped Electrons and ``CO
'' in 
-Irradiated 3-Methylpentane
The singlet ESR signal of -irradiated 3-methylpentane (3-MP) glass [K. Tsuji, H. Yoshida, and K. Hayashi, J. Chem. Phys. 46, 810 (1967)], which is attributable to physically trapped electrons, and the...
-Irradiated 3-MethylpentaneThe singlet ESR signal of -irradiated 3-methylpentane (3-MP) glass [K. Tsuji, H. Yoshida, and K. Hayashi, J. Chem. Phys. 46, 810 (1967)], which is attributable to physically trapped electrons, and the...
Spectroscopic Study of the Vacuum-Ultraviolet Photolysis of Matrix-Isolated HCN and Halogen Cyanides. Infrared Spectra of the Species CN and XNC
J. Chem. Phys. 47, 278 (1967); doi:10.1063/1.1711859
Issue Date: 1 July 1967
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Vacuum-ultraviolet photolysis of HCN isolated in Ar and N2 matrices at 14°K is found to lead to the production of HNC in concentration sufficient for direct infrared observation of all three vibrational fundamentals. The spectrum of this species is found to be appreciably perturbed by the presence of N2. The force constants and thermodynamic properties of HNC have been revised to the values appropriate to this species in an environment free of perturbation by an adjacent N2 molecule. The free radical CN is also produced in these systems in concentration sufficient for direct observation not only of the B(2
+)—X(2+) transition but also of the ground-state vibrational fundamental. Isotopic data supporting this identification are presented. Upon vacuum-ultraviolet photolysis of matrix-isolated FCN, two infrared absorptions appear which can be identified with the stretching fundamentals of the species FNC. In analogous experiments on the species ClCN and BrCN, infrared absorptions tentatively assigned to ClNC and BrNC have been observed.
©1967 American Institute of Physics
+)—X(2+) transition but also of the ground-state vibrational fundamental. Isotopic data supporting this identification are presented. Upon vacuum-ultraviolet photolysis of matrix-isolated FCN, two infrared absorptions appear which can be identified with the stretching fundamentals of the species FNC. In analogous experiments on the species ClCN and BrCN, infrared absorptions tentatively assigned to ClNC and BrNC have been observed.
©1967 American Institute of Physics
| History: | Received 24 February 1967 |
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