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Aluminum monochloride excited states observed by resonance-enhanced multiphoton ionization spectroscopy

J. Chem. Phys. 99, 7521 (1993); doi:10.1063/1.465682

Issue Date: 15 November 1993

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David V. Dearden, Russell D. Johnson III, and Jeffrey W. Hudgens
Chemical Kinetics and Thermodynamics Division, National Institute of Standards and Technology, Gaithersburg, Maryland 20899
AlCl was detected and characterized with 1+2, 2+1, 2+2, 3+1, and 3+2 resonance-enhanced multiphoton ionization spectroscopy using laser light between 332 and 570 nm. AlCl was generated in the gas phase with high temperature reaction of Al with InCl3, or by the reaction of Al with AgCl. New states residing between 52 000 and 66 000 cm−1 were identified. Vibrational intervals of the new Rydberg states are about 20% greater than those of AlCl (X 1Sigma+), with most lying between 565–595 cm−1. The Journal of Chemical Physics is copyrighted by The American Institute of Physics.
History: Received 28 June 1993; accepted 2 August 1993
Permalink: http://link.aip.org/link/?JCPSA6/99/7521/1
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KEYWORDS and PACS

Keywords
PACS
  • 33.60.Cv
    Molecular spectra and interactions of molecules with photons Photoelectron spectra Ultraviolet and vacuum ultraviolet photoelectron spectra
  • 33.80.Rv
    Molecular spectra and interactions of molecules with photons Photon interactions with molecules Multiphoton ionization and excitation to highly excited states (e.g., Rydberg states)
  • 33.10.Gx
    Molecular spectra and interactions of molecules with photons Calculation of molecular spectra Vibrational analysis
  • YEAR: 1993

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ISSN:
0021-9606 (print)   1089-7690 (online)
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REFERENCES (33)
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