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Sticking coefficient for dissociative adsorption of N2 on Ru single-crystal surfaces

J. Chem. Phys. 104, 375 (1996); doi:10.1063/1.470836

Issue Date: 1 January 1996

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H. Dietrich, P. Geng, K. Jacobi, and G. Ertl
Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, D-14195 Berlin, Germany
The dissociative chemisorption of N2 on Ru(0001), Ru(101-bar 0), and Ru(112-bar 1) surfaces at 300 K was studied by means of high-resolution electron energy loss spectroscopy and thermal desorption spectroscopy. The initial sticking coefficient was determined to s0=(1±0.8)×10–12, within the limits of error independent of surface orientation. On Ru(101-bar 0) and Ru(112-bar 1) small amounts of N can be dissolved into the subsurface region. ©1996 American Institute of Physics.
History: Received 7 July 1995; accepted 28 September 1995
Permalink: http://link.aip.org/link/?JCPSA6/104/375/1
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KEYWORDS and PACS

Keywords
PACS
  • 82.65.My
    Physical Chemistry Surface and interface chemistry Chemisorption
  • 82.30.Lp
    Physical Chemistry Specific chemical reactions; reaction mechanisms Decomposition reactions (pyrolysis, dissociation, and group ejection)
  • YEAR: 1996

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ISSN:
0021-9606 (print)   1089-7690 (online)
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REFERENCES (35)
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  1. A. Ozaki and K. Aika, in Catalysis—Science and Technology, edited by J. R. Anderson and M. Boudart (Springer, Berlin, 1981), Vol. 1, p. 87.
  2. G. Ertl, in Catalytic Ammonia Synthesis, edited by J. R. Jennings (Plenum, New York, 1991), p. 109.
  3. P. Stoltze and J. K. Nøvskov, Topics in Catal. 1, 253 (1994).
  4. F. Boszo, G. Ertl, M. Grunze, and M. Weiss, J. Catal. 49, 18 (1977).
  5. F. Boszo, G. Ertl, and M. Weiss, J. Catal. 50, 519 (1977).
  6. G. Ertl, S. B. Lee, and M. Weiss, Surf. Sci. 114, 527 (1982).
  7. S. R. Tennison, in Ref. 2, p. 303.
  8. K. Aika, Angew. Chem., Int. Ed. Engl. 25, 558 (1986).
  9. S. Uchiyama, Y. Hattori, A. Ozaki, and K. Aika, Chem. Lett. 1981, 1463.
  10. G. C. Bond, in The Physical Basis for Heterogeneous Catalysis, edited by E. Drauglis and R. I. Jaffee (Plenum, New York, 1975), p. 33.
  11. A. Ozaki, K. Aika, and H. Hori, Bull. Chem. Soc. Jpn. 44, 3216 (1971).
  12. L. R. Danielson, M. J. Dresser, E. E. Donaldson, and J. T. Dickinson, Surf. Sci. 71, 599 (1978).
  13. T. Matsushima, Surf. Sci. 197, L287 (1988).
  14. K. Kunimori, M. Osumi, S. Kamaeoka, and S. Ito, Catal. Lett. 16, 443 (1992).
  15. J. E. Parmeter, Y. Wang, C. B. Mullins, and W. H. Weinberg, J. Chem. Phys. 88, 5225 (1988).
  16. Y. Zhou, S. Akhter, and J. E. White, Surf. Sci. 202, 357 (1988).
  17. T. Sasaki, T. Aruga, H. Kuroda, and Y. Iwasawa, Surf. Sci. 224, L969 (1989);
    18. Surf. Sci. 240, 223 (1990).
  18. Y. Zhou, Z. M. Liu, and J. M. White, Surf. Sci. 230, 85 (1990).
  19. Y.-K. Sun, Y.-Q. Wang, C. B. Mullins, and W. H. Weinberg, Langmuir 7, 1689 (1991).
  20. J. E. Parmeter, U. Schwalke, and W. H. Weinberg, J. Am. Chem. Soc. 110, 53 (1988).
  21. H. Rauscher, K. L. Kostov, and D. Menzel, Chem. Phys. 177, 473 (1993).
  22. H. Shi, K. Jacobi, and G. Ertl, J. Chem. Phys. 99, 9248 (1993).
  23. M. Gruyters and K. Jacobi, J. Electron Spectrosc. Relat. Phenom. 64/65, 591 (1993).
  24. H. Ibach, Electron Energy Loss Spectrometers—The Technology of High Performance (Springer, Berlin 1991).
  25. G. Kisters, J. G. Chen, S. Lehwald, and. H. Ibach, Surf. Sci. 254, 65 (1991).
  26. G. E. Thomas and W. H. Weinberg, J. Chem. Phys. 70, 954 (1979).
  27. H. Pfnür, P. Feulner, and D. Menzel, J. Chem. Phys. 79, 161 (1983).
  28. H. Dietrich and K. Jacobi (unpublished).
  29. G. Lauth, T. Solomun, W. Hirschwald, and K. Christmann, Surf. Sci. 210, 201 (1989).
  30. H. Dietrich, K. Jacobi, and G. Ertl (unpublished).
  31. F. Rosowski, H. Hinrichsen, M. Muhler, and G. Ertl (unpublished).
  32. K. Aika, T. Takano, and S. Murata, J. Catal. 136, 126 (1992).
  33. P. Feulner and D. Menzel, Phys. Rev. B 25, 4295 (1982).
  34. A. B. Anton, N. R. Avery, T. E. Madey, and W. H. Weinberg, J. Chem. Phys. 85, 507 (1986).
  35. J. Trost, J. Wintterlin, and G. Ertl (unpublished).

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