Journal of Chemical Physics
Feedback | Help | Exit
The Journal of Chemical Physics
Search:
   
 
 
 
Previous Article
Quantum reaction in a condensed phase: Turnover behavior from new adiabatic factorizations and corrections
This paper further investigates quantum activated rate theory from the viewpoint of quantum evolution operators. It is shown that a new adiabatic separation of the quantum system-bath Hamiltonian can,...
Next Article
Yield determination of OH (v=0,1) radicals produced by the electron-ion recombination of protonated molecules
A flowing afterglow apparatus in conjunction with laser induced fluorescence (LIF) diagnostics has been used to determine the yields of OH(X2,  v=0,1) produced by the dissociative recombinat...

Yield determination of OH(v=0,1) radicals produced by the electron-ion recombination of H3O+ ions

J. Chem. Phys. 107, 2430 (1997); doi:10.1063/1.474586

Issue Date: 15 August 1997

You are not logged in to this journal. Log in

Theodosia Gougousi and Rainer Johnsen
Department of Physics and Astronomy, University of Pittsburgh, Pittsburgh, Pennsylvania 15260

Michael F. Golde
Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260
A flowing afterglow apparatus in conjunction with laser induced fluorescence (LIF) diagnostics has been used to determine the yield of OH(v=0,1) produced by the dissociative recombination (DR) of H3O+ ions with electrons at 300 K. The yield for v=0 radicals (0.48 ± 0.07) was determined by two different methods: (1) by comparing it to the known OH yield of the ion-molecule reaction Ar++H2O and (2) by comparing it to that of the reaction of metastable Ar atoms (Ar*) with H2O. The yield of vibrationally excited OH(v=1) (0.12± 0.02) was obtained relative to that in v=0 by comparing LIF spectra. The results corroborate earlier experimental work which determined the yields of OH in v=0 and in unspecified vibrationally excited states v>0. ©1997 American Institute of Physics.
History: Received 12 November 1996; accepted 13 May 1997
Permalink: http://link.aip.org/link/?JCPSA6/107/2430/1
BUY THIS ARTICLE   (US$24)
Download PDF (195 kB) View Cart

KEYWORDS and PACS

Keywords
PACS
  • 34.80.Lx
    Atomic and molecular collision processes and interactions Electron scattering Electronion recombination and electron attachment
  • 33.50.Dq
    Molecular properties and interactions with photons Fluorescence and phosphorescence; radiationless transitions, quenching (intersystem crossing, internal conversion) Fluorescence and phosphorescence spectra
  • YEAR: 1996-97

RELATED DATABASES


To view database links for this article,
you need to log in.
To view database links for this article,
you need to log in.

PUBLICATION DATA

ISSN:
0021-9606 (print)   1089-7690 (online)
Publisher:
AIP is a member of CrossRef AIP

REFERENCES (72)
View in Separate Window/Tab
For access to fully linked references, you need to log in. For access to fully linked references, you need to Log in.
  1. G. C. Reid, Adv. At. Mol. Phys. 63, 375 (1976).
  2. A. Dalgarno and J. H. Black, Rep. Prog. Phys. 39, 573 (1976).
  3. T. J. Millar, D. J. DeFrees, A. D. McLean, and E. Herbst, Astron. Astrophys. 194, 250 (1988).
  4. J. B. Laudenslager, Kinetics of Ion-Molecule Reactions (Plenum, New York, 1979), p. 405.
  5. J. M. Goodings, N. S. Karellas, and C. S. Hassanali, Int. J. Mass Spectrom. Ion Proc. 89, 205 (1989).
  6. G. Turban, Pure Appl. Chem. 56, 215 (1984).
  7. J. B. A. Mitchell, Phys. Rep. 186, 217 (1990).
  8. F. J. Mehr and M. A. Biondi, Phys. Rev. 181, 264 (1969).
  9. C. S. Weller and M. A. Biondi, Phys. Rev. Lett. 19, 59 (1967).
  10. C. M. Huang, M. A. Biondi, and R. Johnsen, Phys. Rev. A 11, 901 (1975).
  11. R. Johnsen, Int. J. Mass Spectrom. Ion Process 81, 67 (1987).
  12. D. Auerbach, R. Cacak, R. Caudano, T. D. Gaily, C. J. Keyser, J. Wm. McGowan, J. B. A. Mitchell, and S. F. J. Wilk, J. Phys. B 10, 3797 (1977).
  13. P. M. Mul, J. Wm. McGowan, P. Defrance, and J. B. A. Mitchell, J. Phys. B 16, 3099 (1983).
  14. F. B. Yousif, J. B. A. Mitchell, M. Rogelstad, A. Le Paddelec, A. Canosa, and M. I. Chibisov, Phys. Rev. A 49, 4610 (1994).
  15. E. Alge, N. G. Adams, and D. Smith, J. Phys. B 16, 1433 (1983).
  16. N. G. Adams and D. Smith, Chem. Phys. Lett. 144, 11 (1988).
  17. A. Canosa, J. C. Gomet, B. R. Rowe, and J. L. Queffelec, J. Chem. Phys. 94, 7159 (1991).
  18. M. Larsson, Int. J. Mass Spectrom. Ion Process 149/150, 403 (1995).
  19. S. Datz, M. Larsson, C. Stromholm, G. Sundström, V. Zengin, H. Danared, A. Källberg, and M. af Ugglas, Phys. Rev. A 52, 2901 (1995).
  20. B. R. Rowe and J. L. Queffelec, Dissociative Recombination: Theory, Experiment and Application (World Scientific, Singapore, 1989), p. 151.
  21. N. G. Adams, Advances in Gas Phase Ion Chemistry (JAI, Greenwich, 1992), Vol. 1, p. 271.
  22. B. L. Foley, N. G. Adams, and H. S. Lee, J. Phys. Chem. 97, 5218 (1993).
  23. N. G. Adams and L. M. Babcock, J. Phys. Chem. 98, 4564 (1994).
  24. M. Tsuji, M. Nakamura, and Y. Nishimura, J. Chem. Phys. 103, 1413 (1995).
  25. B. R. Rowe, F. Vallee, J. L. Queffelec, J. C. Gomet, and M. Morlais, J. Chem. Phys. 88, 845 (1988).
  26. J. L. Queffelec, B. R. Rowe, F. Vallee, J. C. Gomet, and M. Morlais, J. Chem. Phys. 91, 5335 (1989).
  27. N. G. Adams, C. R. Herd, M. Geoghegan, D. Smith, A. Canosa, J. C. Gomet, B. R. Rowe, J. L. Queffelec, and M. Morlais, J. Chem. Phys. 94, 4852 (1991).
  28. N. G. Adams, C. R. Herd, and D. Smith, J. Chem. Phys. 91, 963 (1989).
  29. C. Herd, N. G. Adams, and D. Smith, Astrophys. J. 349, 388 (1990).
  30. J. B. A. Mitchell, J. L. Forand, C. T. Ng, D. P. Levac, R. E. Mitchell, P. M. Mul, W. Clayes, A. Sen, and J. Wm. McGowan, Phys. Rev. Lett. 51, 885 (1983).
  31. S. Datz, G. Sundström, C. Biedermann, L. Broström, H. Danared, S. Mannervik, J. R. Mowat, and M. Larsson, Phys. Rev. Lett. 74, 896 (1995).
  32. W. P. Kraemer and A. U. Hazi, Dissociative Recombination: Theory, Experiment and Application (World Scientific, Singapore, 1989), p. 61.
  33. S. L. Guberman, Physics of Ion-Ion and Electron-Ion Collisions (Plenum, New York, 1983), p. 167.
  34. H. H. Michels and R. H. Hobbs, Astrophys. J. 286, L27 (1984).
  35. S. Green and E. Herbst, Astrophys. J. 229, 121 (1979).
  36. E. Herbst, Appl. J. 222, 508 (1978).
  37. E. T. Galloway and E. Herbst, Astrophys. J. 376, 531 (1991).
  38. D. R. Bates, Astrophys. J. 306, L45 (1986).
  39. D. R. Bates, J. Phys. B 24, 3267 (1991).
  40. D. R. Bates, Astrophys. J. 344, 531 (1989).
  41. T. Gougousi, R. Johnsen, and M. F. Golde, Int. J. Mass Spectrom. Ion Process 149/150, 131 (1995).
  42. R. Johnsen, E. V. Shun'ko, T. Gougousi, and M. F. Golde, Phys. Rev. E 50, 3994 (1994).
  43. A. A. Radzig and B. M. Smirnov, Reference Data on Atoms, Molecules and Ions (Springer, Berlin, 1980).
  44. T. Gougousi, M. F. Golde, and R. Johnsen, Chem. Phys. Lett. 265, 399 (1997).
  45. C. J. Howard, H. W. Rundle, and F. Kaufman, J. Chem. Phys. 53, 3745 (1970).
  46. J. Balamuta, M. F. Golde, and Y. S. Ho, J. Chem. Phys. 79, 2822 (1983).
  47. L. A. Gundel, D. W. Setser, M. A. A. Clyne, J. A. Coxon, and W. Nip, J. Chem. Phys. 64, 4390 (1976).
  48. D. Smith, N. G. Adams, and E. Alge, J. Phys. B 17, 461 (1984).
  49. D. L. Albritton, At. Data Nucl. Tables 22, 1 (1978).
  50. J. H. Kolts, H. C. Brashears, and D. W. Setser, J. Chem. Phys. 67, 2931 (1977).
  51. M. F. Golde, Y. S. Ho, and H. Ogura, J. Chem. Phys. 76, 3535 (1982).
  52. J. Balamuta and M. F. Golde, J. Chem. Phys. 76, 2430 (1982).
  53. T. Gougousi, M. F. Golde, and R. Johnsen (unpublished).
  54. W. H. Press, W. Vetterling, S. A. Teukolsky, and B. Flannery, Numerical Recipes in Fortran, 2nd ed. (Cambridge University Press, Cambridge, 1992), pp. 847, 861.
  55. H. W. Ellis, R. Y. Pai, E. W. McDaniel, E. A. Mason, and L. A. Viehland, At. Data Nucl. Tables 17, 177 (1976).
  56. H. W. Ellis, E. W. McDaniel, D. L. Albritton, L. A. Viehland, S. L. Lin, and E. A. Mason, At. Data Nucl. Tables 22, 179 (1978).
  57. H. W. Ellis, M. G. Thackston, E. W. McDaniel, and E. A. Mason, At. Data Nucl. Tables 31, 113 (1984).
  58. E. W. McDaniel, J. B. A. Mitchell, and M. E. Rudd, Atomic Collisions: Heavy Particle Projectiles (Wiley, New York, 1993), p. 498.
  59. M. T. Leu, M. A. Biondi, and R. Johnsen, Phys. Rev. A 7, 292 (1973).
  60. P. M. Mul, J. Wm. McGowan, P. Defrance, and J. B. A. Mitchell, J. Phys. B 16, 3099 (1983).
  61. N. G. Adams, D. Smith, and E. Alge, J. Chem. Phys. 81, 1778 (1984).
  62. D. Smith and P. Spanel, Int. J. Mass Spectrom. Ion Processes 129, 163 (1993).
  63. G. A. Raiche, J. B. Jeffries, K. J. Rensberger, and D. R. Crosley, J. Chem. Phys. 92, 7258 (1990).
  64. G. H. Dieke and H. M. Crosswhite, J. Quantum Spectrosc. Radiat. Transfer 2, 97 (1962).
  65. D. R. Crosley and R. K. Lengel, J. Quantum Spectrosc. Radiat. Transfer 15, 579 (1975).
  66. K. Schofield, J. Phys. Chem. Ref. Data 8, 723 (1979).
  67. M. F. Golde (unpublished).
  68. J. J. Margitan, F. Kaufman, and J. G. Anderson, Int. J. Chem. Kinet. Symp. No. 1, 281 (1975).
  69. D. Talbi and R. P. Saxon, J. Chem. Phys. 91, 2376 (1989).
  70. D. R. Bates, Mon. Not. R. Astron. Soc. 263, 369 (1993).
  71. L. H. Anderson, O. Heber, D. Kella, H. B. Petersen, L. Vejby-Christensen, and D. Zaifman, Phys. Rev. Lett. 77, 4891 (1966).
  72. T. L. Williams, N. G. Adams, L. M. Babcock, Charles R. Herd, and M. Geoghegan, Mon. Not. R. Astron. Soc. 282, 413 (1966).

CITING ARTICLES
For access to citing articles, you need to log in.
For access to citing articles, you need to Log in.


Copyright © American Institute of Physics