Journal of Chemical Physics
The Journal of Chemical Physics
Search:
   
 
 
 
Previous Article
Electronic instability of isolated SO<sub>4</sub><sup>2 - </sup> and its solvation stabilization
Despite its ubiquity in nature, SO42 - " align="middle"/> as an isolated dianion has never been detected because of its electronic instability as a result of the two negative charges. This study shows...
Next Article
Spectral decomposition and Bloch equation of the operators represented by fixed-centroid path integrals
Interesting approaches to study statical and dynamic properties of quantum systems, e.g., the quantum transition state theory and the centroid molecular dynamics, have been previously derived using fi...

Incorporating physical implementation concerns into closed loop quantum control experiments

J. Chem. Phys. 113, 10841 (2000); doi:10.1063/1.1326905

Issue Date: 22 December 2000

You are not logged in to this journal. Log in

J. M. Geremia, Wusheng Zhu, and Herschel Rabitz
Department of Chemistry, Princeton University, Princeton, New Jersey 08544
In quantum control experiments, it is desirable to build features into the field that address physical concerns such as simplicity, robustness, dynamical coherence, power expenditure, etc. With a judicious choice for the cost functional, it is possible to incorporate such secondary features into the field, often without altering the experimental procedure or apparatus. Through simulated closed-loop population transfer experiments, we demonstrate the benefit of carefully designed cost functionals. As specific examples, we address two common physical concerns: removing extraneous structure from the control pulse and finding robust fields. Removing unnecessary field components is critical if information about the mechanism is to be interpreted from the structure of the optimal pulse. Robust fields produce a stable outcome despite noise in the field and, perhaps, environmental inhomogeneities in the quantum system as is typical of condensed phase experiments. ©2000 American Institute of Physics.
History: Received 20 July 2000; accepted 28 September 2000
Permalink: http://link.aip.org/link/?JCPSA6/113/10841/1
BUY THIS ARTICLE   (US$24)
Download HTML Download Sectioned HTML Download PDF (113 kB) View Cart

KEYWORDS and PACS

Keywords
PACS
  • 03.65.Bz
    Quantum mechanics, field theories, and special relativity Quantum mechanics Foundations, theory of measurement, miscellaneous theories (including Aharonov–Bohm effect, Bell inequalities, Berry's phase)
  • YEAR: 2000

RELATED DATABASES


To view database links for this article,
you need to log in.
To view database links for this article,
you need to log in.

PUBLICATION DATA

ISSN:
0021-9606 (print)   1089-7690 (online)
Publisher:
AIP is a member of CrossRef AIP

REFERENCES (13)

For access to fully linked references, you need to log in. For access to fully linked references, you need to Log in.
  1. R. Judson and H. Rabitz, Phys. Rev. Lett. 68, 1500 (1992).
  2. D. Tannor and S. Rice, J. Chem. Phys. 83, 5013 (1985).
  3. M. Shapiro and P. Brumer, J. Chem. Phys. 84, 4103 (1986).
  4. A. Pierce, M. Dahleh, and H. Rabitz, Phys. Rev. A 37, 4950 (1988).
  5. H. Rabitz, R. de Vivie-Riedle, M. Motzkus, and K. Kompa, Science 288, 824 (2000).
  6. R. Kosloff, S. Rice, P. Gaspard, S. Tersigni, and D. Tannor, J. Chem. Phys. 139, 201 (1989).
  7. T. Weinacht, J. White, and P. Bucksbaum, J. Phys. Chem. A 103, 10166 (1999).
  8. A. Assion, T. Baumbert, T. Bergt, B. Brixner, B. Kiefer, M. Seyfried, M. Strehle, and G. Gerber, Science 282, 919 (1998).
  9. C. Bardeen, V. Yakovlev, K. Wilson, S. Carpenter, P. Weber, and W. Warren, Chem. Phys. Lett. 280, 151 (1997).
  10. K. Bergmann, H. Theuer, and B. Shore, Rev. Mod. Phys. 70, 1003 (1998).
  11. D. Goldberg, Genetic Algorithms in Search, Optimization, and Machine Learning (Addison–Wesley, Reading, MA, 1989).
  12. omega01 = 1.711, omega02 = 3.026, omega03 = 4.134, omega12 = 1.314, omega13 = 2.423, omega23 = 1.108, µ01 = 1.653, µ02 = 0.254, µ03 = 0.000, µ12 = 0.814, µ13 = 0.025, µ23 = 0.059. Frequencies are in rad fs–1 and transition dipole moments in 1.0×10–30 C m.
  13. A. Matsumoto and K. Iwamoto, J. Quant. Spectrosc. Radiat. Transf. 55, 457 (1996).

CITING ARTICLES

For access to citing articles, you need to log in.
For access to citing articles, you need to Log in.