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Connectedness percolation in athermal mixtures of flexible and rigid macromolecules: Analytic theory

J. Chem. Phys. 118, 10787 (2003); doi:10.1063/1.1575201

Issue Date: 15 June 2003

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Xiaoling Wang and Avik P. Chatterjee
Department of Chemistry, SUNY-ESF, Syracuse, New York 13210
A semianalytic theory is developed for calculating percolation thresholds for rod-like nanoparticles dispersed in a flexible polymeric matrix. Methods of macromolecular integral equation theory are combined with the connectedness Ornstein–Zernike equation and an explicitly two-component model in which both the molecules constituting the matrix as well as the filler species are accounted for. The effects on the percolation threshold of explicitly including the matrix species are examined and compared with predictions based on an analogous approach which restricts attention to the rod–rod second virial coefficient. Explicit inclusion of the polymeric matrix does not alter the qualitative dependence of the percolation threshold on rod aspect ratio. However, accounting for the matrix leads to a quantitative reduction of the critical volume fraction by a factor independent of the rod length. Although the present work focuses on the athermal situation (excluded volume interactions alone), the methodology developed in this account can be readily extended to model matrix-filler specific interactions as well. ©2003 American Institute of Physics.
History: Received 31 January 2003; accepted 17 March 2003
Permalink: http://link.aip.org/link/?JCPSA6/118/10787/1
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KEYWORDS and PACS

Keywords
PACS
  • 36.20.-r
    Macromolecules and polymer molecules
  • 61.46.+w
    Structure of nanoscale materials: clusters, nanoparticles, nanotubes, and nanocrystals
  • 64.60.Ak
    Renormalization-group, fractal, and percolation studies of phase transitions
  • YEAR: 2003

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ISSN:
0021-9606 (print)   1089-7690 (online)
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REFERENCES (41)
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For access to fully linked references, you need to log in. For access to fully linked references, you need to Log in.
  1. V. Favier, H. Chanzy, and J. Y. Cavaille, Macromolecules 28, 6365 (1995).
  2. M. Neus Angles and A. Dufresne, Macromolecules 34, 2921 (2001);
  3. M. Paillet and A. Dufresne, ibid. 34, 6527 (2001).
  4. M. A. Sharaf and J. E. Mark, Polymer 43, 643 (2002).
  5. Y. T. Lim, J. H. Park, and O. O. Park, J. Colloid Interface Sci. 245, 198 (2002);
  6. H. Wang, C. Zeng, M. Elkovitch, L. James Lee, and K. W. Koelling, Polym. Eng. Sci. 41, 2036 (2001).
  7. Q. W. Yuan and J. E. Mark, Macromol. Chem. Phys. 200, 206 (1999).
  8. Y. Rharbi, B. Cabane, A. Vacher, M. Joanicot, and F. Boue, Europhys. Lett. 46, 472 (1999);
  9. A. Lee and J. D. Lichtenhan, J. Appl. Polym. Sci. 73, 1993 (1999).
  10. Y. Kantor and I. Webman, Phys. Rev. Lett. 52, 1891 (1984).
  11. W. Y. Hsu and S. Wu, Polym. Eng. Sci. 33, 293 (1993).
  12. Z. Bartczak, A. S. Argon, R. E. Cohen, and M. Weinberg, Polymer 40, 2331 (1999).
  13. K. Yurekli, R. Krishnamoorti, M. F. Tse, K. O. McElrath, A. H. Tsou, and H. C. Wang, J. Polym. Sci., Part B: Polym. Phys. 39, 256 (2001).
  14. G. D. Smith, D. Bedrov, L. Li, and O. Byutner, J. Chem. Phys. 117, 9478 (2002).
  15. B. Budiansky, J. Mech. Phys. Solids 13, 223 (1965).
  16. V. Favier, G. R. Canova, S. C. Shrivastava, and J. Y. Cavaille, Polym. Eng. Sci. 37, 1733 (1997).
  17. K. Leung and D. Chandler, J. Stat. Phys. 63, 837 (1991).
  18. A. P. Chatterjee, J. Chem. Phys. 113, 9310 (2000).
  19. N. P. Shusharina, P. G. Khalatur, and A. R. Khokhlov, J. Chem. Phys. 113, 7006 (2000).
  20. K. S. Schweizer and J. G. Curro, Adv. Chem. Phys. 98, 1 (1997).
  21. D. Chandler, in Studies in Statistical Mechanics, edited by E. W. Montroll and J. L. Lebowitz (North-Holland, Amsterdam, 1982), Vol. VII, p. 274.
  22. A. Coniglio, U. de Angelis, and A. Forlani, J. Phys. A 10, 1123 (1977).
  23. G. Stell, J. Phys.: Condens. Matter 8, A1 (1996).
  24. Y. C. Chiew and E. D. Glandt, J. Phys. A 16, 2599 (1983).
  25. Y. C. Chiew, G. Stell, and E. D. Glandt, J. Chem. Phys. 83, 761 (1985).
  26. A. P. Chatterjee, J. Chem. Phys. 117, 10888 (2002).
  27. L. Harnau and J. P. Hansen, J. Chem. Phys. 116, 9051 (2002).
  28. W. Y. Hsu, M. R. Giri, and R. M. Ikeda, Macromolecules 15, 1210 (1982).
  29. M. Doi and S. F. Edwards, The Theory of Polymer Dynamics (Clarendon, Oxford, 1986).
  30. A. P. Chatterjee and K. S. Schweizer, Macromolecules 31, 2353 (1998).
  31. C. G. Gray and K. E. Gubbins, Theory of Molecular Fluids (Oxford University Press, Oxford, 1984).
  32. I. Balberg, C. H. Anderson, S. Alexander, and N. Wagner, Phys. Rev. B 30, 3933 (1984).
  33. E. J. Garboczi, K. A. Snyder, J. F. Douglas, and M. F. Thorpe, Phys. Rev. E 52, 819 (1995);
    34. Z. Neda, R. Florian, and Y. Brechet, ibid. 59, 3717 (1999).
  34. T. DeSimone, S. Demoulini, and R. M. Stratt, J. Chem. Phys. 85, 391 (1986).
  35. L. A. Pugnaloni and F. Vericat, J. Chem. Phys. 116, 1097 (2002).
  36. P. Terech, L. Chazeau, and J. Y. Cavaille, Macromolecules 32, 1872 (1999).
  37. K. S. Schweizer, Macromolecules 26, 6033 (1993).
  38. X. Wang and A. P. Chatterjee, J. Chem. Phys. 116, 347 (2002).
  39. S. Asakura and F. Oosawa, J. Chem. Phys. 22, 1255 (1954).
  40. A. P. Philipse and A. M. Wieranga, Langmuir 14, 49 (1998).
  41. A. L. R. Bug, S. A. Safran, G. S. Grest, and I. Webman, Phys. Rev. Lett. 55, 1896 (1985).
  42. J. A. Given and G. R. Stell, Physica A 209, 495 (1994);
    43. D. Chandler, J. Phys.: Condens. Matter 3, F1 (1991).
  43. S. H. Munson-McGee, Phys. Rev. B 43, 3331 (1991);
    44. A. Celzard, E. McRae, C. Deleuze, M. Dufort, G. Furdin, and J. F. Mareche, ibid. 53, 6209 (1996).
  44. G. T. Pickett and K. S. Schweizer, J. Chem. Phys. 112, 4869 (2000).

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