Three-photon absorption in anthracene-porphyrin-anthracene triads: A quantum-chemical study
We have applied correlated quantum-chemical methods to investigate the three-photon absorption (3PA) response of a porphyrin triad derivative, where the central macrocycle is linked in mesopositions t...
We have applied correlated quantum-chemical methods to investigate the three-photon absorption (3PA) response of a porphyrin triad derivative, where the central macrocycle is linked in mesopositions t...
Relativistic density-functional all-electron calculations of interconfigurational energies of lanthanide atoms
The interconfigurational energies (ICEs) of the lanthanide atoms, including the s ionization energies, the f ionization energy, and the fd transition energy, are studied based on the fully relativisti...
The interconfigurational energies (ICEs) of the lanthanide atoms, including the s ionization energies, the f ionization energy, and the fd transition energy, are studied based on the fully relativisti...
Nonadiabatic transitions in the exit channel of atom-molecule collisions: Fine-structure branching in Na + N2
J. Chem. Phys. 121, 11068 (2004); doi:10.1063/1.1818121
Issue Date: 8 December 2004
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We study Na + N2 collisions by laser excitation of the collision complex in a differential scattering experiment. The measured relative population of the Na(3p) fine-structure levels reflects the nonadiabatic transitions occuring in the exit channel of the collision. Theoretical results obtained with a classical-path formalism and accurate quantum chemical data for NaN2 are found to be in good agreement. The presence of a conical intersection for the T-shaped geometry has a profound influence on the observed fine-structure branching.©2004 American Institute of Physics.
| History: | Received 6 August 2004; accepted 23 September 2004 |
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http://link.aip.org/link/?JCPSA6/121/11068/1 |
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BibSonomy
KEYWORDS and PACS
sodium,
nitrogen,
sodium compounds,
atom-molecule collisions,
fine structure,
quantum chemistry,
molecular configurations,
photoexcitation,
molecule-photon collisions
- 34.50.Gb
Electronic excitation and ionization of molecules; intermediate molecular states including lifetimes, state mixing, etc - 33.15.Pw
Molecular fine and hyperfine structure - 33.15.Bh
General molecular conformation and symmetry; stereochemistry - 33.80.-b
Photon interactions with molecules - 31.15.-p
Calculations and mathematical techniques in atomic and molecular physics excluding electron correlation calculations - YEAR: 2004
RELATED DATABASES
PUBLICATION DATA
0021-9606 (print)
1089-7690 (online)
AIP
REFERENCES (12)
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- M. H. Alexander, G. Capecchi, and H. Werner,
Science 296, 715 (2002) . - G. C. Schatz, M. Hankel, T. W. J. Whiteley, and J. N. L. Connor,
J. Phys. Chem. A 107, 7278 (2003) . - A. Ermers, T. Woschnik, and B. Behmenburg,
Z. Phys. D: At., Mol. Clusters 5, 113 (1987) . - M. D. Havey, F. T. Delahanty, L. L. Vahala, and G. Copeland, Phys. Rev. A 34, 2758 (1986).
- J. Grosser, O. Hoffmann, F. Schulze Wischeler, and F. Rebentrost, J. Chem. Phys. 111, 2853 (1999).
- C. Figl, A. Grimpe, R. Goldstein et al.,
Russ. J. Phys. Chem. 76 (Suppl. 1), 90 (2002) . - M. Jungen, M. Lehner, M. Guérout, and J. Stalder,
Phys. Chem. Chem. Phys. 6, 1666 (2004) . - D. Spelsberg, F. Rebentrost, and W. Meyer (unpublished).
- J. Grosser, D. Gundelfinger, A. Maetzing, and W. Behmenburg,
J. Phys. B 27, L367 (1994) . - C. Figl, J. Grosser, O. Hoffmann, and F. Rebentrost,
J. Phys. B 37, 3369 (2004) . - C. Figl, J. Grosser, O. Hoffmann, and F. Rebentrost, Europhys. Lett. (submitted).
- R. Goldstein, C. Figl, J. Grosser, O. Hoffmann, M. Jungen, J. Stalder, and F. Rebentrost, J. Chem. Phys. 121, 8769 (2004).
