Quantum optimal control: Hessian analysis of the control landscape
J. Chem. Phys. 124, 204106 (2006); doi:10.1063/1.2198836
Published 25 May 2006
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Seeking an effective quantum control entails searching over a landscape defined as the objective as a functional of the control field. This paper considers the problem of driving a state-to-state transition in a finite level quantum system, and analyzes the local topology of the landscape of the final transition probability in terms of the variables specifying the control field. Numerical calculation of the eigenvalues of the Hessian of the transition probability with respect to the control field variables reveals systematic structure in the spectra reflecting the existence of a generic and simple control landscape topology. An illustration shows that the number of nonzero Hessian eigenvalues is determined by the number of quantum states in the system. The Hessian eigenvectors associated with its nonzero eigenvalues are shown to give insight into the cooperative roles of the control variables. The practical consequences of these findings for quantum control are discussed.
©2006 American Institute of Physics
| History: | Received 6 February 2006; accepted 30 March 2006; published 25 May 2006 |
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http://link.aip.org/link/?JCPSA6/124/204106/1 |
REFERENCES (35)
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- A. H. Zewail, in Femtosecond Chemistry, edited by J. Manz and L. Wöste (Springer-Verlag, Weinheim, 1995), p. 15.
- S. A. Rice and M. Zhao, Optical Control of Molecular Dynamics (Wiley, New York, 2000).
- W. S. Warren, H. Rabitz, and M. Dahleh,
Science 259, 1581 (1993) . - H. Rabitz, R. de Vivie-Riedie, M. Motzkus, and K. Kompa,
Science 288, 824 (2000) . - R. Levis, G. Menkir, and H. Rabitz,
Science 292, 709 (2001) . - C. J. Bardeen, Q. Wang, and C. V. Shank, Phys. Rev. Lett. 75, 3410 (1995).
- A. Assion, T. Baumert, M. Bergt, T. Brixner, B. Kiefer, V. Seyfried, M. Strehle, and G. Gerber,
Science 282, 919 (1998) . - T. Brixner, N. Damrauer, B. Kiefer, and G. Gerber,
Nature (London) 414, 57 (2001) . - R. Gordon and S. Rice,
Annu. Rev. Phys. Chem. 48, 601 (1997) . - M. Shapiro and P. Brumer, J. Chem. Phys. 84, 4103 (1986).
- D. J. Tannor and S. A. Rice, J. Chem. Phys. 83, 5013 (1985).
- S. Shi, A. Woody, and H. Rabitz, J. Chem. Phys. 88, 6870 (1988).
- R. Kosloff, S. A. Rice, P. Gaspard, S. Tersigni, and D. J. Tannor,
Chem. Phys. 139, 201 (1989) . - R. S. Judson and H. Rabitz, Phys. Rev. Lett. 68, 1500 (1992).
- Y. J. Yan, R. E. Gillilan, R. M. Whitnell, K. R. Wilson, and S. Mukamel,
J. Phys. Chem. 97, 2320 (1993) . - K. Bergmann, H. Theuer, and B. W. Shore, Rev. Mod. Phys. 70, 1003 (1998).
- N. F. Scherer, R. J. Carlson, A. Matro, M. Du, A. J. Ruggiero, V. Romero-Rochin, J. A. Cina, G. R. Fleming, and S. A. Rice, J. Chem. Phys. 95, 1487 (1991).
- Z. W. Shen, Y. J. Yan, J. X. Cheng, F. Shuang, Y. Zhao, and G. Z. He, J. Chem. Phys. 110, 7192 (1999).
- O. Mandel, M. Greiner, A. Widera, T. Rom, T. W. Hänsch, and I. Bloch,
Nature (London) 425, 937 (2003) . - U. Dorner, T. Calarco, P. Zoller, A. Browaeys, and P. Grangier,
J. Opt. B: Quantum Semiclassical Opt. 7, 341 (2005) . - S. Suzuki, K. Mishima, and K. Yamashita,
Chem. Phys. Lett. 410, 358 (2005) . - Y. Ohtsuki,
Chem. Phys. Lett. 404, 126 (2005) . - U. Troppmann and R. de Vivie-Riedle, J. Chem. Phys. 122, 154105 (2005).
- D. Babikov, J. Chem. Phys. 121, 7577 (2004).
- T. C. Weinacht, J. L. White, and P. H. Bucksbaum,
J. Phys. Chem. A 103, 10166 (1999) . - H. Rabitz, M. M. Hsieh, and C. M. Rosenthal,
Science 303, 1998 (2004) . - H. Rabitz, T. S. Ho, M. Hsieh, R. Kosut, and M. Demiralp, Phys. Rev. A (submitted).
- D. Cardoza, C. Trallero-Herrero, F. Langhojer, H. Rabitz, and T. Weinacht, J. Chem. Phys. 122, 124306 (2005).
- The derivation of Eq. (7) is fully detailed in Ref. 27, and the present paper demonstrates the validity of this result and considers some of its consequences.
- D. Goldberg, Genetic Algorithms in Search, Optimization and Machine Learning (Addison-Wesley, Reading, 1989).
- F. Yip, D. Mazziotti, and H. Rabitz, J. Chem. Phys. 118, 8168 (2003).
- M. Demiralp and H. Rabitz, Phys. Rev. A 47, 831 (1993).
- The simulation labels 1, 2,
, 8, respectively, corresponding to the transition probability yields of 0.9999, 0.9526, 0.9010, 0.8342, 0.7091, 0.6043, 0.5115, and 0.3981. - The eigenvalues in Fig. 4 differ from those in Figs. 7 and 8 due to the scaling arising from using different control variables [i.e.,
(tk) in Fig. 4 and
i and
i in Figs. 7 and 8] which is embodied in Eq. (8). - J. Geremia, W. Zhu, and H. Rabitz, J. Chem. Phys. 113, 10841 (2000).








