Ionization and fragmentation of isomeric van der Waals complexes embedded in helium nanodroplets
The ionization and charge transfer processes, which occur when a doped helium droplet undergoes electron impact, are studied for droplets doped with van der Waals complexes with various structures and...
The ionization and charge transfer processes, which occur when a doped helium droplet undergoes electron impact, are studied for droplets doped with van der Waals complexes with various structures and...
Implementation of the full explicitly correlated coupled-cluster singles and doubles model CCSD-F12 with optimally reduced auxiliary basis dependence
An implementation of the full explicitly correlated coupled-cluster singles and doubles model CCSD-F12 using a single Slater-type geminal has been obtained with the aid of automated term generation an...
An implementation of the full explicitly correlated coupled-cluster singles and doubles model CCSD-F12 using a single Slater-type geminal has been obtained with the aid of automated term generation an...
Simultaneous optical excitation of Na electronic and CF4 vibrational modes in Na+CF4 collisions
J. Chem. Phys. 129, 201102 (2008); doi:10.1063/1.3028653
Published 24 November 2008
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We report on the ultraviolet excitation of Na(3s)+CF4 collision pairs in a crossed molecular beam experiment. We observe Na(3d) collision products originating from the process Na(3s)+CF4(
3=0)+h
Na(3d)+CF4(3=1). The spectral intensity distribution of the collision products and the prevailing small angle scattering confirm a previously proposed long range dipole-dipole mechanism. We report velocity-resolved spectra and a comparison to preliminary numerical results based on collisional broadening theory. Polarization experiments suggest future potential for the observation of collision geometries.
©2008 American Institute of Physics
3=0)+hNa(3d)+CF4(3=1). The spectral intensity distribution of the collision products and the prevailing small angle scattering confirm a previously proposed long range dipole-dipole mechanism. We report velocity-resolved spectra and a comparison to preliminary numerical results based on collisional broadening theory. Polarization experiments suggest future potential for the observation of collision geometries.
©2008 American Institute of Physics
| History: | Received 30 September 2008; accepted 30 October 2008; published 24 November 2008 |
| Permalink: |
http://link.aip.org/link/?JCPSA6/129/201102/1 |
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BibSonomy
KEYWORDS and PACS
atom-molecule collisions,
atom-photon collisions,
molecule-photon collisions,
organic compounds,
photoexcitation,
rotational-vibrational energy transfer,
Rydberg states,
sodium,
spectral line intensity
- 34.50.Ez
Rotational and vibrational energy transfer (atoms and molecules) - 32.80.-t
Photoionization and excitation of atoms - 32.70.Fw
Atomic absolute and relative intensities - 33.70.Fd
Molecular absolute and relative line and band intensities - 31.50.Df
Potential energy surfaces for excited electronic states (atoms and molecules) - 33.80.-b
Photon interactions with molecules - YEAR: 2008
RELATED DATABASES
PUBLICATION DATA
0021-9606 (print)
1089-7690 (online)
AIP
REFERENCES (10)
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- J. Grosser, O. Hoffmann, and F. Rebentrost, in Atomic and Molecular Beams. The State of the Art 2000, edited by R. Campargue (Springer, New York, 2001), p. 485.
- T. Schmidt, C. Figl, A. Grimpe, J. Grosser, O. Hoffmann, and F. Rebentrost, Phys. Rev. Lett. 92, 033201 (2004).
- V. A. Alekseev and N. Schwentner,
Chem. Phys. Lett. 463, 47 (2008) . - A. A. Radzig and B. M. Smirnov, Reference Data on Atoms, Molecules, and Ions (Springer, Berlin, 1985).
- A. H. McDaniel, C. A. Cantrell, J. A. Davidson, R. E. Shetter, and J. G. Calvert,
J. Atmos. Chem. 12, 211 (1991) . - V. A. Alekseev and N. Schwentner,
Chem. Phys. Lett. 436, 327 (2007) . - C. Figl, J. Grosser, O. Hoffmann, and F. Rebentrost,
Chem. Phys. Lett. 380, 196 (2003) . - G. Herzberg, Molecular Spectra and Molecular Structure II: Infrared and Raman Spectra of Polyatomic Molecules (Van Nostrand, Toronto, 1957).
- L. I. Gudzenko and S. I. Yakovlenko, Zh. Eksp. Teor. Fiz. 62, 1686 (1972).
- S. Geltman, Phys. Rev. A 35, 3775 (1987), and references therein.
