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Tracing ultrafast hydrogen migration in allene in intense laser fields by triple-ion coincidence momentum imaging
Ultrafast hydrogen migration in allene (CH2=C=CH2) in intense laser fields was investigated by triple-ion coincidence momentum imaging. The migrating proton covering the entire range of an allene mole...

Direct visualization of the H–Xe bond in xenon hydrides: Xenon isotopic shift in the IR spectra

J. Chem. Phys. 131, 151101 (2009); doi:10.1063/1.3250426

Published 16 October 2009

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Vladimir I. Feldman,1,2 Alexey V. Kobzarenko,1 Irina A. Baranova,1 Alexander V. Danchenko,1 Fedor F. Sukhov,1 Ehud Tsivion,3 and R. Benny Gerber3,4
1Department of Chemistry, Moscow State University, Moscow 119991, Russia
2Institute of Synthetic Polymer Materials, Russian Academy of Sciences, 70 Profsoyuznaya Street, Moscow 117393, Russia
3Department of Physical Chemistry, The Hebrew University, Jerusalem 91904, Israel
4Department of Chemistry, University of California, Irvine, California 92697-2025, USA
IR spectra of xenon hydrides (HXeCCH, HXeCC, and HXeH) obtained from different xenon isotopes (129Xe and 136Xe) exhibit a small but detectable and reproducible isotopic shift in the absorptions assigned to H–Xe stretching (by 0.17–0.38  cm−1). To our knowledge, it is the first direct experimental evidence for the H–Xe bond in HXeY type compounds. The shift magnitude is in good agreement with quantum-chemical calculations. ©2009 American Institute of Physics
History: Received 8 September 2009; accepted 24 September 2009; published 16 October 2009
Permalink: http://link.aip.org/link/?JCPSA6/131/151101/1
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KEYWORDS and PACS

Keywords
PACS
  • 33.15.Fm
    Molecular bond strengths, dissociation energies
  • 33.70.Jg
    Molecular line and band widths, shapes, and shifts
  • 33.20.Ea
    Infrared molecular spectra
  • YEAR: 2009

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PUBLICATION DATA

ISSN:
0021-9606 (print)   1089-7690 (online)
Publisher:
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