Hydrophobic effects on multivalent-salt-induced self-condensation of DNA
Hydrophobic effects on multivalent-salt-induced self-condensation of a single polyelectrolyte chain such as DNA are investigated through a multiscale coarse-grained simulation based on density functio...
Hydrophobic effects on multivalent-salt-induced self-condensation of a single polyelectrolyte chain such as DNA are investigated through a multiscale coarse-grained simulation based on density functio...
Ubiquitous T-shaped isomers of OCS-hydrocarbon van der Waals complexes
Many weakly bound OCS-hydrocarbon complexes exhibit a relatively simple rotation-vibration band, characteristic of a T-shaped structure, which is redshifted (by 5–12 cm−1) from ...
Many weakly bound OCS-hydrocarbon complexes exhibit a relatively simple rotation-vibration band, characteristic of a T-shaped structure, which is redshifted (by 5–12 cm−1) from ...
Grand potential in thermodynamics of solid bodies and surfaces
J. Chem. Phys. 131, 161104 (2009); doi:10.1063/1.3254324
Published 26 October 2009
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Using the chemical potential of a solid in a dissolved state or the corresponding component of the chemical potential tensor at equilibrium with the solution, a new concept of grand thermodynamic potential for solids has been suggested. This allows generalizing the definition of Gibbs' quantity 
(surface work often called the solid-fluid interfacial free energy) at a planar surface as an excess grand thermodynamic potential per unit surface area that (1) does not depend on the dividing surface location and (2) is common for fluids and solids.
©2009 American Institute of Physics
(surface work often called the solid-fluid interfacial free energy) at a planar surface as an excess grand thermodynamic potential per unit surface area that (1) does not depend on the dividing surface location and (2) is common for fluids and solids.
©2009 American Institute of Physics
| History: | Received 6 July 2009; accepted 5 October 2009; published 26 October 2009 |
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http://link.aip.org/link/?JCPSA6/131/161104/1 |
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