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Journal of The Electrochemical Society

A Model of Electrocodeposition on a Rotating Cylinder Electrode

J. Electrochem. Soc., Volume 154, Issue 2, pp. D70-D77 (2007)

(Published 19 December 2006)

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Jaesung Lee and Jan B. Talbot
Chemical Engineering Program, University of California, San Diego, La Jolla, California 92093-0411, USA
A model of particle electrocodeposition on a rotating cylinder electrode was developed to predict the incorporated particle volume fraction in a composite film. Asymptotic solutions to the transport equations for ions within the diffusion boundary layer showed that diffusion of the reactive species in a supporting electrolyte solution is the dominant process to carry current at the cathodic surface. The ratio of the total volume of particles to that of the deposited metal was expressed as a function of two transport parameters, current density, a probability to determine the particle surface concentration, and two experimental fitting parameters.

©2006 The Electrochemical Society
History: Submitted 22 May 2006; revised 13 September 2006; published 19 December 2006
Permalink: http://dx.doi.org/10.1149/1.2398819

KEYWORDS and PACS

Keywords
PACS
  • 82.45.Qr
    Electrodeposition and electrodissolution
  • 81.15.Pq
    Electrodeposition, electroplating
  • 82.45.Fk
    Electrodes
  • 66.30.Dn
    Theory of diffusion and ionic conduction in solids
  • 82.45.Gj
    Electrolytes (electrochemistry)
  • YEAR: 2007

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PUBLICATION INFORMATION

ISSN:
0013-4651 (print)  
Publisher:
AIP is a member of CrossRef ECS
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