Potential-Correlation Function Duality in Statistical Mechanics
J. Math. Phys. 8, 2143 (1967); doi:10.1063/1.1705132
Issue Date: October 1967
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The Feynman path-integral formulation is used to analyze the grand-partition function Z and the n-body Green's function Gn or rather their cumulants (or connected parts)
n for a system governed by p-body interaction potentials vp. It is shown that the functional relationship expressing
n in terms of vp is invariant under the transformation exchanging −(−)m
m and vm everywhere. Under the same transformation log Z undergoes a change of sign. The content of these results is discussed in conclusion.
©1968 The American Institute of Physics
| History: | Received 12 April 1967 |
| Permalink: |
http://link.aip.org/link/?JMAPAQ/8/2143/1 |
PUBLICATION DATA
0022-2488 (print)
1089-7658 (online)
REFERENCES (10)
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- J. Yvon, Act. Sci. Ind. 203 (1935), to quote the earliest attempt known to the authors, where the one-body potential is eliminated in favor of the “observable” one-body density, yielding, in particular, the so-called virial expansion.
- See, for example, the review article of C. Bloch, Studies in Statistical Mechanics (North-Holland Publishing Company, Amsterdam, 1965), Vol. 3, p. 1.
- A perturbation expansion approach to this result viewed in the framework of field theory together with comments on possible applications to “bootstrap” theory of interaction is being published elsewhere; F. Englert and C. De Dominicis, Nuovo Cimento (to be published).
- Section 20 of Ref. 2 discusses the pseudoperiodicity conditions imposed on many-“time” potentials.
- See, for example, N. N. Bogoliubov and D. V. Shirkov, Introduction to the Theory of Quantized Fields (Interscience Publishers, Inc., New York, 1959),
- and J. S. Bell in The Many-Body Problem, E. Caianiello, Ed. (Academic Press, Inc., New York, 1962), for its quantum statistical mechanics aspect.
- Results of Table I remain valid if the factors (i)p+q or (i)n+m are suppressed everywhere (this immediately follows from the structure of the diagram expansions, for example). In that form, however, the propagator has an opposite sign. Results of Ref. 3 for field theory are recovered by the substitutions
and
, where
is the usual energy variable. - See, for example, S. F. Edwards,
Phil. Mag. 4, 1171 (1959) for classical systems; - B. Mühlschlegel and H. Zittartz,
Z. Physik 175, 553 (1963) for Ising systems. - J. Yvon, Les corrélations et I'entropie en mécanique statistique classique (Cie Dunod, Paris, 1966). Equations (19) and (20) of the text are his equations (4) and (5), Chap. 2, Sec. 2.
- J. Yvon, Cours de Mécanique Statistique à la Faculté des Sciences de Paris (1966).
- C. De Dominicis and F. Englert (to be published).







