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IUPAC-NIST Solubility Data Series. 87. Rare Earth Metal Chlorides in Water and Aqueous Systems. Part 1. Scandium Group (Sc, Y, La)

J. Phys. Chem. Ref. Data 37, 1765 (2008); doi:10.1063/1.2956740

Published 15 October 2008

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Tomasz Mioduski
Institute of Nuclear Chemistry and Technology, Warsaw, Poland

Cezary Gumiński
Department of Chemistry, University of Warsaw, Warsaw, Poland

Dewen Zeng
College of Chemistry and Chemical Engineering, Hunan University, Hunan, People's Republic of China
This volume presents solubility data for rare earth metal chlorides in water and in ternary and quaternary aqueous systems. The material is divided into three parts: scandium group (Sc, Y, La), light lanthanide (Ce-Eu), and heavy lanthanide (Gd-Lu) chlorides; this part covers the scandium group. Compilations of all available experimental data are introduced for each rare earth metal chloride with a corresponding critical evaluation. Every such evaluation contains a tabulated collection of all solubility results in water, a scheme of the water-rich part of the equilibrium (Y, La, Ln)Cl3–H2O phase diagram, solubility equation(s), a selection of suggested solubility data, and a discussion of the multicomponent systems. Because the ternary and quaternary systems were almost never studied more than once, no critical evaluations or systematic comparisons of such data were possible. Only simple chlorides (no complexes) are treated as the input substances in this work. The literature (including a thorough coverage of papers in Chinese and Russian) has been covered through the middle of 2007. ©2008 American Institute of Physics
History: Received 12 May 2008; revised 20 May 2008; accepted 20 May 2008; published 15 October 2008
Permalink: http://link.aip.org/link/?JPCRBU/37/1765/1
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KEYWORDS and PACS

Keywords
PACS
  • 64.75.Bc
    Solubility
  • 82.60.Lf
    Thermodynamics of solutions (chemistry)
  • YEAR: 2008

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0047-2689 (print)   1529-7845 (online)
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