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Phys. Rev. E 73, 031106 (2006) [8 pages]

Exactly solvable disordered sphere-packing model in arbitrary-dimensional Euclidean spaces

S. Torquato
Department of Chemistry, Princeton University, Princeton, New Jersey 08544, USA; Program in Applied and Computational Mathematics, Princeton University, Princeton New Jersey, 08544, USA; and PRISM, Princeton University, Princeton, New Jersey 08544, USA

F. H. Stillinger
Department of Chemistry, Princeton University, Princeton, New Jersey 08544, USA
Received 15 September 2005; published 9 March 2006

We introduce a generalization of the well-known random sequential addition (RSA) process for hard spheres in d-dimensional Euclidean space [openface R]d. We show that all of the n-particle correlation functions of this nonequilibrium model, in a certain limit called the "ghost" RSA packing, can be obtained analytically for all allowable densities and in any dimension. This represents the first exactly solvable disordered sphere-packing model in an arbitrary dimension. The fact that the maximal density phi([infinity])=1/2d of the ghost RSA packing implies that there may be disordered sphere packings in sufficiently high d whose density exceeds Minkowski's lower bound for Bravais lattices, the dominant asymptotic term of which is 1/2d. Indeed, we report on a conjectural lower bound on the density whose asymptotic behavior is controlled by 2–(0.778 65...)d, thus providing the putative exponential improvement on Minkowski's 100-year-old bound. Our results suggest that the densest packings in sufficiently high dimensions may be disordered rather than periodic, implying the existence of disordered classical ground states for some continuous potentials.

©2006 The American Physical Society

URL: http://link.aps.org/doi/10.1103/PhysRevE.73.031106
DOI: 10.1103/PhysRevE.73.031106
PACS: 05.20.-y; 61.20.-p
  • 05.20.-y
    Classical statistical mechanics
  • 61.20.-p
    Structure of liquids
  • YEAR: 2006
KEYWORDS: random processes, lattice theory, ground states

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