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Phys. Rev. A 74, 061402(R) (2006) [4 pages]OH hyperfine ground state: From precision measurement to molecular qubits
Received 18 August 2006; published 21 December 2006
We perform precision microwave spectroscopy—aided by Stark deceleration—to reveal the low-magnetic-field behavior of OH in its 2 ©2006 The American Physical Society
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3/2 rovibronic ground state, identifying two field-insensitive hyperfine transitions suitable as qubits and determining a differential Landé g factor of 1.267(5)×10−3 between opposite-parity components of the 
doublet. The data are successfully modeled with an effective hyperfine Zeeman Hamiltonian, which we use to make a tenfold improvement of the magnetically sensitive, astrophysically important 
F=±1 satellite-line frequencies, yielding 1 720 529 887(10) Hz and 1 612 230 825(15) Hz.
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